trans-Rh(PPh3)2(CO)(triflate) | 116466-22-9

• 英文名称: trans-Rh(PPh3)2(CO)(triflate)
• 英文别名: trans-Rh(PPh3)2(CO)(CF3SO3)
• CAS: 116466-22-9
• 化学式: C₃₈H₃₀F₃O₄P₂RhS
• 分子量: 804.568
• InChiKey: UDLUEILBJPUZIZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-Rh(PPh3)2(CO)(triflate) 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 以0%的产率得到carbonyl(hydroxy)bis(triphenylphosphine)rhodium(I)
  参考文献：
  名称：

  Araghizadeh, Farshid; Branan, Daniel M.; Hoffman, Norris W., Inorganic Chemistry, 1988, vol. 27, # 21, p. 3752 - 3755

  摘要：

  DOI：
• 作为产物：
  描述：

  以 氘代氯仿 为溶剂， 生成 trans-Rh(PPh3)2(CO)(triflate)
  参考文献：
  名称：

  Ready formation of stable cationic Rh(I) complexes of MeCN, formamide, urea and related species via replacement of the triflate in trans-(Ph3P)2Rh(CO)(OTf)

  摘要：

  The weakly-coordinated trifluoromethanesulfonate (triflate) in trans-(Ph3P)2Rh(CO)(OTf) (OTf = OSO2CF3) can be readily replaced by ligand L to form stable ionic complexes [trans-(Ph3P)2RhL(CO)]OTf (L = MeCN, formamide pyrone and urea). The replacement of triflate by carbon monoxide forms an unstable species that gradually loses CO and returns the starting material. Sterically hindered ligands such as 1,1,3,3-tetramethylurea and xanthone do not react.

  DOI：

  10.1016/s0020-1693(00)80926-3

文献信息

• Ligand redistribution reactions of some organometallic rhodium and iridium complexes
  作者：Peter J. Stang、Yo-Hsin Huang

  DOI：10.1016/0022-328x(92)83470-3

  日期：1992.2

  Ligand redistribution reactions of some organometallic rhodium and iridium complexes have been investigated and their possible reaction pathways have been discussed.

  研究了一些有机金属铑和铱配合物的配体再分布反应，并讨论了其可能的反应途径。
• Song, Linsheng; Arif, Atta M.; Stang, Peter J., Organometallics, 1990, vol. 9, # 10, p. 2792 - 2797
  作者：Song, Linsheng、Arif, Atta M.、Stang, Peter J.

  DOI：——

  日期：——
• Evaluation of Triflate Displacement by Water in CH₂Cl₂ Solution:  Comparison of <i>trans</i>-[Rh(CO)(PPh₃)₂(OSO₂CF₃)] and the Crystalline Salt <i>trans</i>-[Rh(CO)(PPh₃)₂(OH₂)][OTf]
  作者：Anna Svetlanova-Larsen、John L. Hubbard

  DOI：10.1021/ic951287h

  日期：1996.1.1
• Formation and characterization of simple, stable, coordinated water complexes of rhodiumand iridium. The crystal structure of trans-[Rh(PPh3)2(CO)(H3O]+CF3SO3−
  作者：Peter J. Stang、Linsheng Song、Yo-Hsin Huang、Atta M. Arif

  DOI：10.1016/0022-328x(91)86299-6

  日期：1991.3

  Reaction of trans-(Ph3P)2Rh(CO)(OSO2CF3) and trans-(Ph3P)2Ir(CO)(OSO2CF3) with water in benzene results in the formation of stable trans-[(Ph3P)2Rh(CO)(H2O)] + CF3SO3- and trans-[(Ph3P)2Ir(CO)(H2O)] + CF3SO3-, respectively. The crystal structure of the Rh-complex is reported.
• Reactivity studies of square planar platinum, iridium, and rhodium triflate complexes with alkynols
  作者：Peter J. Stang、Yo-Hsin Huang

  DOI：10.1016/0022-328x(92)80122-e

  日期：1992.6

  The reactions of trans-Pt(OTf)(CH3)(PPh3)2, trans-Ir(OTf)(CO)(PPh3)2, and trans-Rh(OTf)(CO) (PPh3)2 with 3-butyn-1-ol and 4-pentyn-2-ol have been investigated.