density for the unpaired electron. The results are discussed in term of oxidation states. Furthermore, the parent complex was investigated for light-induced linkage isomerisation using IR spectroscopy. Thermally and optically reversible generation of a new species identified by new vibrational bands is interpreted in terms of photoinduced nitrosyl linkage isomers.
配合物[Fe(CO)2(NO)2 ]的电
化学以及一电子还原的[Fe(CO)2(NO)2 ]的IR和EPR光谱-和单电子氧化的物种[Fe(CO)2(NO)2 ]+主要显示未配对电子的以NO为中心的自旋密度。根据氧化态讨论了结果。此外,使用红外光谱研究了母体复合物的光诱导键异构化。根据光诱导的亚
硝酰基键合异构体解释了由新的振动带识别的新物种的热和光可逆生成。