1,1'-dicarboxylic cobalticinium iodide | 545389-82-0

• 英文名称: 1,1'-dicarboxylic cobalticinium iodide
• 英文别名: [(η(5)-C5H4COOH)2Co]I
• CAS: 545389-82-0
• 化学式: C₁₂H₁₀CoO₄*I
• 分子量: 404.107
• InChiKey: JDISHVJLXPONES-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-dimethylcobalticinium hydroxyde 、 氢碘酸 在 KMnO₄ 、 NaOH 作用下， 以 水 为溶剂， 生成 1,1'-dicarboxylic cobalticinium iodide
  参考文献：
  名称：

  有机金属酸 [(η5-C5H4COOH)2CoIII]+ 与 HBr 和 HI 的反应。[(η5-C5H4COOH)2CoIII]Br和[(η5-C5H4COOH)2CoIII]I的制备与表征及阳离子间氢桥

  摘要：

  The water soluble dicarboxylic cationic acid [(eta(5) -C5H4COOH)(2)Co-III](+) (1) as its Cl- salt has been treated thermally to produce the neutral zwitterion [(eta(5)-C5H4COOH)(eta(5)-C5H4COO)Co-III] (2). 2 reacts with HBr in water solution to yield the bromide salt of the dicarboxylic acid [(eta(5)-C5H4-COOH)(2)Co-III]Br, 1Br. Preparation of the iodide [(eta(5)-C5H4-COOH)(2)Co-III]I, II, has been achieved by direct oxidation of [(eta(5)-C5H4Me)(2)Co-III]OH with KMnO4 immediately followed by reaction with HI. The crystal structures of 1Br and 1I have been determined by single crystal X-ray diffraction. The hydrogen bonding interactions between the acid cations and between the acid cation and the halide ions, have been investigated. (C) 2003 Elsevier Science B.V. All rights reserved..

  DOI：

  10.1016/s0022-2860(02)00508-2