(m-carboranyl)COOC6H3(OEt)CHO | 1064705-50-5

• 英文名称: (m-carboranyl)COOC6H3(OEt)CHO
• CAS: 1064705-50-5
• 化学式: C₁₂H₂₀B₁₀O₄
• 分子量: 336.398
• InChiKey: HCWDHTRKNLRGDC-UHFFFAOYSA-N

物化性质

• 熔点：
  96-97 °C(Solvent: Ethanol)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (m-carboranyl)COOC6H3(OEt)CHO 、 1,3-丙二醇 在 sulfo cation exchanger FIBAN K-1 作用下， 以 苯 为溶剂， 以83%的产率得到4-(1,3-dioxan-2-yl)-2-ethoxyphenyl [m-(C)-carboranyl]methanoate
  参考文献：
  名称：

  Synthesis of 2-R-1,3-dioxanes, derivatives of functionally substituted aldehydes of vanillin series

  摘要：

  By the condensation of substituted aldehydes of vanillin series with 1,3-propanediol in boiling benzene in the presence of sulfo cation exchanger FIBAN K-1 as catalyst functionally 2-R-substituted 1,3-dioxanes were synthesized.

  DOI：

  10.1134/s1070428013020085

文献信息

• Synthesis of functionally substituted 2,2′-arylmethylenebis(3-hydroxy-5,5-dimethylcyclohex-2-enones)
  作者：E. A. Dikusar、V. I. Potkin、S. K. Petkevich、R. M. Zolotar’、O. P. Chepik

  DOI：10.1134/s1070363214070068

  日期：2014.7
• Synthesis of 2-alkoxy-4-[N-(alkyl, cycloalkyl, aryl)imino]phenyl m-carboranecarboxylates
  作者：E. A. Dikusar、V. I. Potkin、A. P. Yuvchenko、N. G. Kozlov、T. D. Zvereva、M. P. Bey

  DOI：10.1134/s1070363207090162

  日期：2007.9

  Previously unknown m-carborane-containing azomethines (Schiff bases) were synthesized by the reaction of esters derived from vanillin or vanillal and m-carboranecarboxylic acid with primary amines in absolute methanol.
• Synthesis of 1,3- and 1,4-bis-methoxy- and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethylene- and phenylmethyl]phenylenediamines
  作者：E. A. Dikusar、V. I. Potkin、N. G. Kozlov、A. P. Kadutskii、A. P. Yuvchenko、M. P. Bey、A. V. Shchurivskaya

  DOI：10.1134/s1070363208110121

  日期：2008.11

  1,3- and 1,4-bis[3-methoxy and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethylene]phenylenediamines were synthesized from the vanillin and vanillal m-carborane-C-carboxylates by the reaction with 1,3- and 1,4-phenylenediamines in anhydrous methanol. Reduction of the title compounds with Na[BH(OAc)(3)] in benzene yielded 1,3- and 1,4-bis[3-methoxy- and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethyl] phenylenediamines.