Na[H2B(mt)2] provides respectively [W(NO)(CO)2HB(mt)3}] and [W(NO)(CO)2(PPh3)κ2-S,S′-H2B(mt)2}]. The complexes [M(NO)(CO)2HB(mt)3}] and [M(NO)(CO)2κ3-H,S,S′-H2B(mt)2}] (M = W, Mo) arise from the reactions of Na[M(CO)3H2B(mt)2}] with N-methyl-N-nitrosotoluenesulfonamide. The molybdenum complex [Mo(NO)(CO)2HB(mt)3}] is also obtained unexpectedly from the reaction of [Mo(η3-C3H5)(CO)2HB(mt)3}] with
一个范围内,聚(methimazolyl)
硼酸亚
硝酰-ligated
钨络合物和
钼被报告的的合成,表征,其中包括所述化合物的晶体结构的测定[W(NO)(CO)2 κ 3 - S,S ',S'' -HB(
MT)3 }],[W(NO)(CO)2(PPH 3)κ 2 - S,S' -H 2 B(
MT)2 }]和[沫( NO)(CO)2 κ 3 - H,S,S' -H 2 B(
MT)2 }](
MT = methimazoyl)。[W(NO)(CO)3(PPh 3)2的反应具有Na [HB(
MT)3 ]和Na [H 2 B(
MT)2 ]的] PF 6分别提供[W(NO)(CO)2 HB(
MT)3 }]和[W(NO)(CO )2(PPH 3)κ 2 - S,S' -H 2 B(
MT)2 }]。配合物[M(NO)(CO)2 HB(
MT)3 }]和[M(NO)(CO)2 κ 3 - H,S,S'