[iridium(III)Cl(3,4-diphenylcinnoline)2]2 | 1244773-98-5

• 英文名称: [iridium(III)Cl(3,4-diphenylcinnoline)2]2
• 英文别名: [Ir(3,4-diphenylcinnoline)2(μ-Cl)]2；[Ir2(μ-Cl)2(dpci-H)4]；[Ir(dpci)2(μ-Cl)]2
• CAS: 1244773-98-5
• 化学式: C₈₀H₅₂Cl₂Ir₂N₈
• 分子量: 1580.69
• InChiKey: WPWAHZCFNDGJEZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [iridium(III)Cl(3,4-diphenylcinnoline)2]2 、 sodium carbazole dithiocarbamate 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Phosphorescent iridium(III) carbodithioate complex for the detection of Hg2+ and acetonitrile

  摘要：

  A cyclometalated iridium(III) complex Ir(dpci)(2)(cbd) (Ir1, dpciH = 3, 4-diphenylcinnoline, cbd = N-carbazolylcarbodithioate) has been prepared and confirmed by H-1 NMR, C-13 NMR, MS, and crystal data. Ir1 could be used as a phosphorescent chemosensor for Hg2+ and acetonitrile (ACN). Upon addition of aqueous Hg2+, the ACN solution of Ir1 gave a visual color change and significant phosphorescent enhancing (130-fold) at 580 nm (OFF-ON). Ir1 has been developed as an AND logic gate with Hg2+ and ACN as inputs. The dissociation of Ir1 and coordination with ACN are response for the sensor process. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.09.031
• 作为产物：
  描述：

  iridium(III) chloride 、 3,4-diphenylcinnoline 以 乙二醇乙醚 、 水 为溶剂， 生成 [iridium(III)Cl(3,4-diphenylcinnoline)2]2
  参考文献：
  名称：

  Phosphorescent iridium(III) carbodithioate complex for the detection of Hg2+ and acetonitrile

  摘要：

  A cyclometalated iridium(III) complex Ir(dpci)(2)(cbd) (Ir1, dpciH = 3, 4-diphenylcinnoline, cbd = N-carbazolylcarbodithioate) has been prepared and confirmed by H-1 NMR, C-13 NMR, MS, and crystal data. Ir1 could be used as a phosphorescent chemosensor for Hg2+ and acetonitrile (ACN). Upon addition of aqueous Hg2+, the ACN solution of Ir1 gave a visual color change and significant phosphorescent enhancing (130-fold) at 580 nm (OFF-ON). Ir1 has been developed as an AND logic gate with Hg2+ and ACN as inputs. The dissociation of Ir1 and coordination with ACN are response for the sensor process. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.09.031

文献信息

• A highly selective chemosensor for mercury(II) cations based on cyclometalated iridium(III) complex
  作者：Bihai Tong、Qunbo Mei、Mangeng Lu

  DOI：10.1016/j.ica.2012.05.017

  日期：2012.8

  Abstract A cyclometalated iridium(III) complex, Ir(dpci) 2 (dtc) ( Ir1 , dpci = 3,4-diphenylcinnoline, dtcH = diethyl dithiocarbamic acid), was synthesized from the reaction of the iridium complex [Ir(dpci) 2 (Cl)] 2 and dtcNa in methanol/CH 2 Cl 2 , and characterized by FT-IR, 1 H NMR and mass spectroscopies. The photoluminescence spectrum of Ir1 shows emission maximum at 686 nm with a lifetime of

  摘要从铱配合物[Ir（dpci）2的反应中，合成了一种环金属化的铱（III）配合物Ir（dpci）2（dtc）（Ir1，dpci = 3,4-diphenylcinnoline，dtcH =二乙基二硫代氨基甲酸）。 （Cl）] 2和dtcNa在甲醇/ CH 2 Cl 2中的溶液，并通过FT-IR，1 H NMR和质谱进行表征。Ir1的光致发光光谱在686 nm处显示最大发射，寿命为0.77μs，PL量子产率为。0.021。此外，含有二硫代氨基甲酸酯辅助配体的[Ir（dpci）2（dtc）]可以用作Hg 2+的高选择性开启化学计量仪，这与二硫代氨基甲酸酯辅助配体从配合物中的解离有关。
• Synthesis, Crystal Structure and Luminescence Properties of a Cyclometalated Ir(III) Complex of 3,4-Diphenylcinnoline
  作者：Bi-Hai Tong、Fang-Hui Wu、Qun-Bo Mei、Qian-Feng Zhang

  DOI：10.1515/znb-2010-0412

  日期：2010.4.1

  An iridium(III) complex, [(dpci-H)₂Ir(dafo)](PF₆) (dpci-H = deprotonated 3,4-diphenylcinnoline, dpci; dafo = 4,5-diazafluoren-9-one), was synthesized from the reaction of the iridium complex [Ir(dpci-H)₂(Cl)]₂ and dafo in methanol, and characterized by single-crystal X-ray diffraction along with FT-IR, UV/Vis, ¹H NMR and mass spectroscopy. The luminescence properties and the decay of the cyclometalated iridium(III) complex were also investigated. Excitation at the absorption wavelength (469 nm) resulted in a strong emission band centered at 591 nm with a lifetime of 0.9 μs.

  一种铱(III)配合物，[(dpci-H)₂Ir(dafo)](PF₆) (dpci-H = 去质子化的3,4-二苯基茜芦啉，dpci; dafo = 4,5-二氮杂芴-9-酮)，通过在甲醇中反应铱配合物[Ir(dpci-H)₂(Cl)]₂和dafo合成，并通过单晶X射线衍射、FT-IR、UV/Vis、¹H NMR和质谱进行表征。还研究了环金属铱(III)配合物的发光性质和衰减。在吸收波长(469 nm)激发下，产生了一个中心波长为591 nm的强发射带，寿命为0.9微秒。