(μ-9,10-bis(diphenylphosphino)anthracene)(AuCl)2 | 574703-53-0

• 英文名称: (μ-9,10-bis(diphenylphosphino)anthracene)(AuCl)2
• 英文别名: [Au₂(μ-9,10-bis(diphenylphosphino)anthracene)Cl₂]；(μ-9,10-bis(diphenylphosphino)anthracene)(AuCl)₂；(μ-dpp)(AuCl)₂；Au2(μ-9,10-bis(diphenylphosphino)anthracene)Cl2
• CAS: 574703-53-0
• 化学式: C₃₈H₂₈Au₂Cl₂P₂
• 分子量: 1011.43
• InChiKey: QYQCMZVMGAWBSV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (μ-9,10-bis(diphenylphosphino)anthracene)(AuCl)2 在 AgSbF₆ 作用下， 以 not given 为溶剂， 生成 [(μ-9,10-bis(diphenylphosphino)anthracene)Au2](2+)
  参考文献：
  名称：

  First Examples of Au^I−X−Ag^I Halonium Cations (X = Cl and Br)

  摘要：

  Novel {[(mu-PAnP)(AuX)2]2Ag}+SbF6- halonium ions (X = Cl, Br; PAnP = 9,10-bis(diphenylphosphino)anthracene) were synthesized from the reactions between (mu-PAnP)(AuX)2 and 1/2 mol equiv of AgSbF6. The compounds feature an unprecedented distorted Au4X4 dodecahedron which encapsulates a silver(I) ion at its center. The halonium ions are stabilized by collective actions of metallophilic Au-Ag, aromatic pi-pi, and Ag-X interactions.

  DOI：

  10.1021/ja035064z
• 作为产物：
  描述：

  氯(二甲基硫化)金(I) 、 9,10-bis(diphenylphosphino)anthracene 以 二氯甲烷 为溶剂， 生成 (μ-9,10-bis(diphenylphosphino)anthracene)(AuCl)2
  参考文献：
  名称：

  First Examples of Au^I−X−Ag^I Halonium Cations (X = Cl and Br)

  摘要：

  Novel {[(mu-PAnP)(AuX)2]2Ag}+SbF6- halonium ions (X = Cl, Br; PAnP = 9,10-bis(diphenylphosphino)anthracene) were synthesized from the reactions between (mu-PAnP)(AuX)2 and 1/2 mol equiv of AgSbF6. The compounds feature an unprecedented distorted Au4X4 dodecahedron which encapsulates a silver(I) ion at its center. The halonium ions are stabilized by collective actions of metallophilic Au-Ag, aromatic pi-pi, and Ag-X interactions.

  DOI：

  10.1021/ja035064z

文献信息

• Self-Assembly and Molecular Recognition of a Luminescent Gold Rectangle
  作者：Ronger Lin、John H. K. Yip、Ke Zhang、Lip Lin Koh、Kwok-Yin Wong、Kam Piu Ho

  DOI：10.1021/ja0456508

  日期：2004.12.1

  = NO(3)(-) or OTf(-)), synthesized from the self-assembly of the molecular "clip" Au(2)(micro-PAnP)(OTf)(2) and bipy, shows a large rectangular cavity of 7.921(3) x 16.76(3) A. The electronic absorption and emission spectroscopy, and electrochemistry of the metallacyclophane, have been studied. The 1(4+) ions are self-assembled into 2D mosaic in the solid state via complementary edge-to-face interactions

  发光分子矩形 [Au(4)(micro-PAnP)(2)(micro-bipy)(2)](OTf)(4) (1.(OTf)(4)) (PAnP = 9,10-bis (diphenylphosphino)anthracene, bipy = 4,4'-bipyridine, X = NO(3)(-) 或 OTf(-))，由分子“夹子”Au(2)(micro-PAnP )(OTf)(2) 和 bipy，显示 7.921(3) x 16.76(3) A 的大矩形腔。已经研究了金属环烷的电子吸收和发射光谱以及电化学。1(4+) 离子通过Ph 基团之间互补的边对面相互作用在固态下自组装成二维马赛克。(1) H NMR 滴定确认 1(4+) 和各种芳族分子之间的 1:1 络合。比较包合物的结构表明在结合中起作用的诱导契合机制。1(4+) 的发射在客体结合时被淬灭。结合常数由 (1) H NMR 和荧
• A dynamic tetranuclear gold(<scp>i</scp>)-cyclophane – gold(<scp>i</scp>)-centred chirality and fluxionality arising from an intramolecular shift of Au–S bonds
  作者：Pau Lin Ang、Van Ha Nguyen、John H. K. Yip

  DOI：10.1039/d1dt01984h

  日期：——

  A tetranuclear gold(I) complex [Au4(μ-PAnP)2(μ-L)2] (PAnP = 9,10-bis(diphenylphosphino)anthracene and L = benzene-1,2-dithiolate) has been synthesized and characterised by multinuclear NMR and X-ray crystallography. The molecule has a cyclophane-like structure which can be considered to be composed of two [Au2(μ-PAnP)(μ-L)] units held together by Au–S bonds and aurophilic interactions (Au–Au = 3.0712(2)

  合成了四核金 ( I ) 配合物 [Au 4 (μ-PAnP) 2 (μ-L) 2 ]（PAnP = 9,10-双（二苯基膦）蒽和 L = 苯-1,2-二硫醇盐）并用多核 NMR 和 X 射线晶体学表征。该分子具有类环芳烃结构，可以认为是由两个 [Au 2 (μ-PAnP)(μ-L)] 单元组成，这些单元通过 Au-S 键和亲热相互作用（Au-Au = 3.0712(2 ） 一种）。L 充当螯合和桥接配体，其中一个 S 原子与两个 Au 离子键合为锍离子，并且环芳的每一侧有两个 Au 2 S 2核。每个 Au 2 S 2 中的一个硫原子核心是手性锍离子，与两个化学性质不同的金离子键合。两个 Au 离子在不对称环境中与四个原子（2S、P 和 Au）键合，使它们成为以金 ( I ) 为中心的手性的罕见例子。两个Au 2 S 2核具有R Au、R S和S Au、S S构型，锍离子和金离子的手性是相关的。变温
• Structures and luminescence properties of diethyldithiocarbamate-bridged polynuclear gold(<scp>i</scp>) cluster complexes with diphosphine/triphosphine
  作者：Jia Li、Xiao-Feng Zhu、Li-Yi Zhang、Zhong-Ning Chen

  DOI：10.1039/c5ra01831e

  日期：——

  4·2CH2Cl2, 2.9288(9)–3.0514(10) Å in 5·2CH2Cl2·H2O, and 2.9236(12)–3.1914(17) Å in 6, implying significant aurophilic interactions. These gold(I) complexes exhibit intense photoluminescence properties in solid state. Upon lowering the temperature from 298 to 77 K, complexes 5 and 6 exhibit an obvious red-shift from 536 nm to 589 nm for 5 and from 538 nm to 564 nm for 6, implying significant luminescence

  一系列的多核金（我）具有桥接二乙基二配合物（ET 2 DTC）和二膦/ triphosphine合成，包括[的Au 2（μ-DPB）（μ-ET 2 DTC）}的SBF 6 ] Ñ（1，DPB = 1,4-双（二苯基膦基）苯），[金2（μ-DPB）（ET 2 DTC）2 ]（2），[金4（μ-DPN）（μ-ET 2 DTC）3 ]（SBF 6）（3，DPN = 1,4-双（二苯基膦基）萘），[金4（μ-DPN）（μ-ET 2 DTC）3] [Au（Et 2 dtc）2 ]（SBF 6）2（4），[Au 4（μ-dpa）（Et 2 dtc）3 ]（SBF 6）（5，dpa = 9,10-双（二苯基膦基） ）蒽）和[Au 6（dpep）2（Et 2 dtc）3 } （SBF 6）3 }] n（6，dpep =双（2-二苯基膦基乙基）苯基膦）。的结构3 ·CH 2氯2，4 ·2CH 2氯2，
• Hetero- and homoleptic binuclear gold(<scp>i</scp>)–thiolate and –halide complexes – ligand exchange kinetics and supramolecular structures
  作者：Pau Lin Ang、Van Ha Nguyen、John H. K. Yip

  DOI：10.1039/d1dt04245a

  日期：——

  [Au2(μ-PAnP)(SPh)(X)], [Au2(μ-PAnP)(SPh)2] and [Au2(μ-PAnP)(X)2], in solution. A solution of [Au2(μ-PAnP)(Cl)2] and [Au2(μ-PAnP)(Br)2] in 1 : 1 molar ratio shows two singlets, implying that the exchange is not due to the dissociation of either PAnP or halide ligands, but rather it involves the exchange of the thiolate and the halide ligands (SPh− ↔ X−). A mixture of [(PPh3)Au(SPh)] and [(PPh3)Au(Cl)] (1 : 1

  异配和同配双核 Au( I ) 配合物[Au 2 (μ-PAnP)(SPh)(X)] (X = Cl -或 Br - ), [Au 2 (μ-PAnP)(SPh) 2 ]和[Au 2 (μ-PAnP)(SPhCO 2 H) 2 ] (SPh = 苯硫醇盐和 SPhCO 2 H = 4-硫醇基苯甲酸) 含有桥联二膦，9,10-双(二苯基膦基)蒽 (PAnP)，合成和表征单晶X射线衍射。[Au 2 (μ-PAnP)(SPh) 2 ]在其晶体中以单体形式存在，但[Au 2 (μ-PAnP)(SPhCO 2 H) 2 ]通过分子间氢键聚合成锯齿形链。[Au 2 (μ-PAnP)(SPh)(Cl)]通过分子间的亲金相互作用在晶体中形成C i对称的类环烷二聚体（Au-Au 距离 = 3.3081(5) Å）。[Au 2 (μ- PAnP )(SPh)(Br)]的再结晶总是导致由[Au 2 (μ-PAnP)(SPh)(Br)]和[Au