[(η5-C5Me5)Ru(CD3CN)3]PF6 | 102538-51-2

• 英文名称: [(η5-C5Me5)Ru(CD3CN)3]PF6
• CAS: 102538-51-2
• 化学式: C₁₆H₂₄N₃Ru*F₆P
• 分子量: 513.349
• InChiKey: DALOQQHOUYEGQB-XVEAFJGJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氘代乙腈 、 [[(pentamethylcyclopentadienyl)Ru]2(η(5),η(5)-2,2':5',2''-terthiophene)](PF6)2 以 氘代乙腈 为溶剂， 生成 [(η5-C5Me5)Ru(CD3CN)3]PF6
  参考文献：
  名称：

  Graf, David D.; Day, Nancy C.; Mann, Kent R., Inorganic Chemistry, 1995, vol. 34, # 6, p. 1562 - 1575

  摘要：

  DOI：

文献信息

• A Transition-Metal-Catalyzed Enediyne Cycloaromatization
  作者：Joseph M. O'Connor、Seth J. Friese、Betsy L. Rodgers

  DOI：10.1021/ja050060a

  日期：2005.11.30

  The pentamethylcyclopentadienyl iron cation, generated from [(eta5-C5Me5)Fe(NCMe)3]PF6, triggers the room temperature cycloaromatization of acyclic and alicyclic enediynes, in the presence of either 1,4-cyclohexadiene or terpinene as the hydrogen-atom donor, to give metal-arene products in good to excellent yields. Photolysis of the metal-arene complexes liberates the arene from the metal in excellent yield. The first demonstration of a transition-metal-catalyzed cycloaromatization of conjugated enediynes has been achieved under photochemical conditions utilizing either [(eta5-C5Me5)Fe(NCMe)3]PF6 or [(eta5-C5Me5)Fe(eta6-1,2-(Prn)2C6H4)]PF6 as the catalyst precursor. The use of a metal and light has led to a convenient method for cycloaromatization of a trans-enediyne.
• McNair, Amy M.; Mann, Kent R., Inorganic Chemistry, 1986, vol. 25, # 15, p. 2519 - 2527
  作者：McNair, Amy M.、Mann, Kent R.

  DOI：——

  日期：——