[Ir(1,5-cyclooctadiene)2]ClO4 | 88492-76-6

• 英文名称: [Ir(1,5-cyclooctadiene)2]ClO4
• 英文别名: [Ir(cod)2]ClO4
• CAS: 88492-76-6
• 化学式: C₁₆H₂₄Ir*ClO₄
• 分子量: 508.037
• InChiKey: IWSAKMZFBBHBBP-QMDOQEJBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir(1,5-cyclooctadiene)2]ClO4 在 CO 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Ruiz, A.; Claver, C.; Rodriguez, J. C., Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：

文献信息

• Preparation and catalytic activity of cationic rhodium(I) and iridium(I) complexes with phosphine sulphide ligands
  作者：C. Claver、F. Gili、J. Viñas、A. Ruiz

  DOI：10.1016/s0277-5387(00)80891-8

  日期：1987.1

  The preparation and properties of cationic rhodium and iridium complexes of types [M(diolefin)L2](ClO4) and [M(diolefin)L(PPh3)](ClO4) [M = Rh, diolefin = 1,5-cyclooctadiene (COD) or 2,5-norbornadiene; M = Ir, diolefin = COD; L = phosphine sulphide] are described. The complexes have been characterized by IR, 1H NMR and 31P NMR spectroscopy. The use of [M(diolefin)L2](ClO4) as catalyst precursors in

  [M（二烯烃）L 2 ]（ClO 4）和[M（二烯烃）L（PPh 3）]（ClO 4）型阳离子铑和铱配合物的制备和性质[M = Rh，二烯烃= 1,5 -环辛二烯（COD）或2,5-降冰片二烯; M = Ir，二烯烃= COD；描述了L ＝硫化膦。该复合物已通过IR，1 H NMR和31 P NMR光谱表征。研究了[M（二烯烃）L 2 ]（ClO 4）在烯烃均相加氢中作为催化剂前体的应用。
• Diolefin cationic iridium(I) complexes with sulfur ligands
  作者：C. Claver、J.C. Rodriguez、A. Ruiz

  DOI：10.1016/s0022-328x(00)98783-7

  日期：1983.8

  preparation and properties of cationic iridium(I) complexes of the types [Ir2(μ-L)2(COD)2](ClO4)2 and [Ir2μ-(L-L)2(COD)2](ClO4)2 (COD = 1,5-cyclooctadiene, L and L-L = mono- and bi-dentate sulfur donor ligand, respectively) are described. The mononuclear complexes [Ir(COD)L2]ClO4 are also described. Reaction with triphenylphosphine gives pentacoordinated mixed complexes of the types [Ir2(μ-L)2(COD)2(PPh3)2](ClO4)2

  类型的制备和阳离子铱的性质（I）配合物的[Ir 2（μ-L）2（COD）2 ]（CLO 4）2和物[Ir 2 μ-（LL）2（COD）2 ]（CLO 4）2（COD = 1,5-环辛二烯，L和LL分别为单齿和双齿硫供体配体）。还描述了单核络合物[Ir（COD）L 2 ] ClO 4。与三苯膦反应生成[Ir 2（μ-L）2（COD）2（PPh 3）2类型的五配位混合配合物]（ClO 4）2，[Ir（COD）L 2（PPh 3）] ClO 4和[Ir（COD）L（PPh 3）2 ] ClO 4。
• Syntheses and structural characterization of [2.2]paracyclophane complexes of rhodium and iridium supported by diene ligands
  作者：Masahiko Maekawa、Naoki Hashimoto、Kunihisa Sugimoto、Takayoshi Kuroda-Sowa、Yusaku Suenaga、Megumu Munakata

  DOI：10.1016/s0020-1693(02)01340-3

  日期：2003.2

  respectively. In contrast, in complexes 4, 5 and 7b, two Rh or Ir atoms are η6-coordinated to the upper and lower decks in the pcp ligand to provide a dinuclear structure. The Rh or Ir atoms are similarly supported by diene ligands. Two coordinating cod ligands in pcp complexes 4 and 7b are located in a staggered conformation against the pcp ligand, whereas two nbd ligands in complex 5 are located in an eclipse

  我们系统制备的Rh和Ir中的9 [2.2]对环芳烷络合物，铑[Rh（η 6 -pCP）（C 2 H ^ 4）2 ] BF 4 ·THF 1 ·THF（PCP = [2.2]对环芳烷），铑[Rh（η 6 -pCP）（二烯）] BF 4（二烯= 1,5-环辛二烯（COD）2 ·CH 2氯2 ; 2,5-降冰片二烯（NBD）3），铑[Rh 2（η 6，η 6 -pCP ）（二烯）2 ]（BF 4）2（二烯=鳕鱼4 ; NBD 5），物[Ir（η 6-pCP）（COD）] X（X = BF 4 6A ; CLO 4图6b ·CH 2氯2）和物[Ir 2（η 6，η 6 -pCP）（COD）2 ] X 2（X = BF 4 7a中； ClO 4 7b），其七个结构在晶体学上得到了表征。在配合物1 ·THF，2 ·CH 2氯2，3和图6b ·CH 2氯2中，每个上的Rh或IR原子是η 6-键合到pCP
• Rhodium(I) and iridium(I) complexes of Ph2P(S)CH2P(S)Ph2, bis(diphenylphosphino)methane disulfide
  作者：M.S. Abbassioun、P.A. Chaloner、C. Claver、P.B. Hitchcock、A.M. Masdeu、A. Ruiz、T. Saballs

  DOI：10.1016/0022-328x(91)83104-c

  日期：1991.2

  Rhodium(I) and iridium(I) complexes of the ligand bis(diphenylphosphino)methane disulphide (dppmS2) have been prepared and characterised. The structures of [Rh(dppmS2)(cod)][ClO4] and [Rh(dppmS2(CO)2][ClO4] were established in diffraction studies, the latter complex adopting an interesting pseudo-dimeric structure in the solid state.

  已经制备并表征了配体双（二苯基膦基）甲烷二硫化物（dppmS 2）的铑（I）和铱（I）配合物。在衍射研究中建立了[Rh（dppmS 2）（cod）] [ClO 4 ]和[Rh（dppmS 2（CO）2 ] [ClO 4 ]的结构，后者的配合物中采用了有趣的伪二聚体结构。固体状态。