| 183112-31-4

• CAS: 183112-31-4
• 化学式: C₁₇H₁₇ClN₂O₂Ti
• 分子量: 364.667
• InChiKey: KYSZORCDRJFJHM-ZEJRMQKLSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 air 作用下， 以 二氯甲烷 为溶剂， 以96%的产率得到[TiCl(salen)]2(μ-O)
  参考文献：
  名称：

  Reactivity of AlMe3 with titanium(IV) Schiff base complexes: X-ray structure of [Ti{(μ-Br)(AlMe2)}{(μ-Br)(AlMe2X)}(salen)] · C7H8 (X=Me or Br) and reactivity studies of mono-alkylated [Ti(Me)X(L)] complexes

  摘要：

  [TiCl2(salen)] (1) reacts with AlMe3 (1:2) to give the heterometallic Ti(III) and Ti(IV) complexes [Ti{(mu-Cl)(AlMe2)}{(mu-Cl)(AlMe2X)}(salen)] (X = Me or Cl) (2) and [TiMe{(mu-Cl)(AlCl2Me)}(salen)] (3). Addition of diethyl ether to 3 affords [Ti(Me)Cl(salen)] (4). The analogous reaction of [TiBr2(salen)] (5) gives the crystallographically characterised [Ti{(mu-Br)(AlMe2)}{(mu-Br)(AlMe2X)}(salen)] (X = Me or Br) (6) and [Ti(Me)Br(salen)] (7) in a single step, whilst the comparable reaction of [TiCl2{(3-MeO)(2)salen}] (8) with AlMe3 yields [Ti(Me)Cl{(3-MeO)(2)salen}] (9) with no evidence of titanium(III) species. Reactivity of both halide and methyl groups of 4 has been probed using magnesium reduction, SbCl5 and AgBF4 halide abstraction and SO2 insertion reactions. Hydrolysis of [Ti(Me)X(L)] complexes affords mu-oxo species [TiX(L)](2)(mu-O) [X = Cl, L = salen (13); X = Br, L = salen (14); X = Cl, L = (3-MeO)(2)salen (15)]. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01167-x
• 作为产物：
  描述：

  乙醚 、 [TiMe((μ-Cl)(AlCl2Me))(salen)] 以 乙醚 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Reactivity of AlMe3 with titanium(IV) Schiff base complexes: X-ray structure of [Ti{(μ-Br)(AlMe2)}{(μ-Br)(AlMe2X)}(salen)] · C7H8 (X=Me or Br) and reactivity studies of mono-alkylated [Ti(Me)X(L)] complexes

  摘要：

  [TiCl2(salen)] (1) reacts with AlMe3 (1:2) to give the heterometallic Ti(III) and Ti(IV) complexes [Ti{(mu-Cl)(AlMe2)}{(mu-Cl)(AlMe2X)}(salen)] (X = Me or Cl) (2) and [TiMe{(mu-Cl)(AlCl2Me)}(salen)] (3). Addition of diethyl ether to 3 affords [Ti(Me)Cl(salen)] (4). The analogous reaction of [TiBr2(salen)] (5) gives the crystallographically characterised [Ti{(mu-Br)(AlMe2)}{(mu-Br)(AlMe2X)}(salen)] (X = Me or Br) (6) and [Ti(Me)Br(salen)] (7) in a single step, whilst the comparable reaction of [TiCl2{(3-MeO)(2)salen}] (8) with AlMe3 yields [Ti(Me)Cl{(3-MeO)(2)salen}] (9) with no evidence of titanium(III) species. Reactivity of both halide and methyl groups of 4 has been probed using magnesium reduction, SbCl5 and AgBF4 halide abstraction and SO2 insertion reactions. Hydrolysis of [Ti(Me)X(L)] complexes affords mu-oxo species [TiX(L)](2)(mu-O) [X = Cl, L = salen (13); X = Br, L = salen (14); X = Cl, L = (3-MeO)(2)salen (15)]. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01167-x