(phenylphosphine)tetracarbonyl iron | 38967-73-6

• 英文名称: (phenylphosphine)tetracarbonyl iron
• 英文别名: Fe(CO)4PPhH2
• CAS: 38967-73-6
• 化学式: C₁₀H₇FeO₄P
• 分子量: 277.984
• InChiKey: PMBCMIFCTWKWDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二苯基氯化膦 、 (phenylphosphine)tetracarbonyl iron 在 三乙胺 作用下， 以 乙醚 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Baacke, Michael; Morton, Stephen; Johannsen, Gerd, Chemische Berichte, 1980, vol. 113, # 4, p. 1328 - 1342

  摘要：

  DOI：
• 作为产物：
  描述：

  五羰基铁 、 苯基膦 以 正辛烷 为溶剂， 以80%的产率得到(phenylphosphine)tetracarbonyl iron
  参考文献：
  名称：

  Reaktionen koordinierter liganden

  摘要：

  DOI：

  10.1016/s0022-328x(00)89154-8

文献信息

• Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH₂ and μ-PPhH Complexes FeMn(CO)₈(μ-PH₂) and FeMn(CO)₈(μ-PPhH)
  作者：Adam C. Colson、Kenton H. Whitmire

  DOI：10.1021/om100736m

  日期：2010.10.25

  Deprotonation of Fe(CO)(4)PRH2 and treatment with Mn(CO)(5)Br afforded the dinuclear complexes FeMn(CO)(8)(mu-PRH) (1a, R = H; 1b, R = Ph), which contain the relatively rare mu-PH2 and mu-PPhH functionalities. The heterometallic nature of these complexes was confirmed by mass spectrometry, and the molecular structures of 1a and 1b were determined by X-ray diffraction experiments. Deprotonation of 1b and subsequent addition of Mn(CO)(5)Br or AuPPh3Cl yielded the trinuclear complexes FeMn(CO)(8)[mu-PPh(Mn(CO)(5))] (3a) and FeMn(CO)(8)[mu-PPh(AuPPh3)] (3b), both of which were characterized structurally and spectroscopically. Deprotonation of 1a at room temperature resulted in rapid coupling of the deprotonated product [2a](-) with neutral 1a to form M+[FeMn(CO)8(mu(3)-PH)Mn(CO)(4)(mu-PH2)Fe(CO)(4)](-) (M+[4](-)) (M+ = Li+, Na+, K+), the formation of which was observed using in situ infrared spectroscopy. M+[4](-) was found to decompose upon solvent removal, and the structure of [4](-) was elucidated by examination of spectroscopic data. The H-1 NMR spectrum of [4](-) was characterized by first-order [ABMX] and [AMX] spin systems, and ESI-MS data confirmed that [4](-) was formed by direct coupling of [2a](-) with 1a without concomitant fragmentation or loss of CO ligands. Deprotonation of 1a at lower temperatures slowed the coupling process, allowing for the metalation of the monomeric anion [2a](-) by treatment with AuPPh3Cl, the product of which was found to decompose gradually in solution and rapidly upon concentration.
• Mueller, Manfred; Vahrenkamp, Heinrich, Chemische Berichte, 1983, vol. 116, # 6, p. 2311 - 2321
  作者：Mueller, Manfred、Vahrenkamp, Heinrich

  DOI：——

  日期：——