| 17595-21-0

• CAS: 17595-21-0
• 化学式: C₁₁H₅FeNO₄
• 分子量: 271.012
• InChiKey: FZAFOMHVAGMVON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 1-异苯甲腈 在 cobalt(II) chloride hexahydrate 作用下， 以 苯 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Albers, Michel O.; Coville, Neil J.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1982, p. 1069 - 1080

  摘要：

  DOI：
• 作为产物：
  描述：

  五羰基铁 、 1-异苯甲腈 在 cobalt(II) chloride hexahydrate 作用下， 以 苯 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Albers, Michel O.; Coville, Neil J.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1982, p. 1069 - 1080

  摘要：

  DOI：

文献信息

• Specific formation of isocyanide iron complexes by reaction of primary carbamoyl ferrates with oxalylchloride
  作者：Denis Luart、Jean-Yves Salaün、Véronique Patinec、René Rumin、Hervé des Abbayes

  DOI：10.1016/s0020-1693(02)01553-0

  日期：2003.7

  Reaction of primary carbamoyl ferrates (CO)4Fe[C(O)NHR]}− (R=Me, Et, allyl, decyl, cyclohexyl, t-butyl, benzyl, phenyl) with 1/2 equiv. of oxalylchloride affords cis-bis-carbamoyl intermediates: (CO)4Fe[C(O)NHR]2 which thermally give rise, in good yields, to the mono-isocyanide complexes (CO)4Fe(CNR). The mechanism of the reaction is discussed. Via a similar process, an alkoxycarbamoyl intermediate

  氨基甲酸酯基高铁酸酯（CO）4 Fe [C（O）NHR]} -（R = Me，Et，烯丙基，癸基，环己基，叔丁基，苄基，苯基）与1/2当量的反应。乙二酰氯的氯化物提供了顺式-双氨基甲酰基中间体：（CO）4 Fe [C（O）NHR] 2，其以良好的收率热生成单-异氰化物配合物（CO）4 Fe（CNR）。讨论了反应机理。通过类似的方法，烷氧基氨基甲酰基中间体（CO）4 Fe [C（O）NHR]（CO 2 Me）得到Fe（CO）5和1,3-二烷基脲。
• The preparation and spectra of [Fe2(η-C5H5)2(CO)4−n(CNAr)n] complexes. The reaction of [Fe(CO)5−m(CNAr)m] with dicyclopentadiene
  作者：A.R. Manning、Gerard McNally、Paul Soye

  DOI：10.1016/s0020-1693(00)83073-x

  日期：1991.2

  The relatively elusive [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] complexes where n = 1 or 2 and Ar = C6H5, 2-MeC6H4, 4-MeC6H4, 2,4-Me2C6H3, 2,6-Me2C6H3 and 2,4,6-Me3C6H2 have been prepared by two effective, but not completely general routes. One is the light-catalyzed substitution of [Fe2(eta-C5H5)2(CO)4] by ArNC which gives the derivatives where n = 1 or 2 and, eventually, 4. The other is the reaction at 145-degrees-C of dicyclopentadiene with [Fe(CO)5] and ArNC or with [Fe(CO)4(CNAr)], but not with [Fe(CO)3(CNAr)2] or [Fe(CO)4(CNMe)]. The pathway of the reaction of dicyclopentadiene with [Fe(CO)5]or[Fe(CO)4(CNAr)] is discussed and it is concluded that it does not proceed via cyclopentadine and mononuclear cyclopentadienyl complexes but via species containing dicyclopentadiene and two metal atoms which are formed at an early stage in the reaction and which remain associated throughout the reaction up to the formation of the [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] derivatives. The infrared and H-1 NMR spectra of the complexes are reported and discussed.
• Reactions of dianionic carbonylmetalates with heteroallenes: reduction of carbonyl sulfide, isothiocyanates, isocyanates, and carbodiimides by Group 6 and 8 carbonylmetalates
  作者：Gary R. Lee、N. John Cooper

  DOI：10.1021/om00108a027

  日期：1989.6