(.+-.)-Fe(CO)4(2-(ethylphenylphosphino)pyridine-P) | 249631-30-9

• 英文名称: (.+-.)-Fe(CO)4(2-(ethylphenylphosphino)pyridine-P)
• 英文别名: (+/-)-Fe(CO)4(2-(ethylphenylphosphino)pyridine-P)
• CAS: 249631-30-9
• 化学式: C₁₇H₁₄FeNO₄P
• 分子量: 383.123
• InChiKey: HVBQUAZPDMSHJV-SLUOLVIESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (.+-.)-Fe(CO)4(2-(ethylphenylphosphino)pyridine-P) 、 mercury dichloride 以 二氯甲烷 为溶剂， 以57%的产率得到(+)-(R)-Fe(CO)4(2-(ethylphenylphosphino)pyridine)HgCl2
  参考文献：
  名称：

  Formation of donor–acceptor Fe(0)–Hg(II) bond in separation and stabilization of optically active iron(0) phosphine complexes. Absolute configuration of (+)-(R)-(CO)4Fe(μ-EtPhPpy)HgCl2

  摘要：

  The chiral phosphine ligand 2-(ethylphenylphosphino)pyridine (EtPhPpy, R/S mixture) reacts with Fe(CO)(5) to give racemic (+/-)-Fe(CO)(4)(EtPhPpy-P), which undergoes an addition reaction with HgCl2 to afford the optically active binuclear Fe(0)-Hg(II) complexes (+)-(R)-(CO)(4)Fe(mu-EtPhPpy)HgCl2 and (-)-(S)-(CO)(4)Fe(mu-EtPhPpy)HgCl2, which can be separated manually in crystalline form. The absolute configuration of (+)-(R)-(CO)(4)Fe(mu-EtPhPpy)HgCl2 has been determined by single crystal X-ray analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00216-9
• 作为产物：
  描述：

  五羰基铁 、 (+/-)-2-(ethylphenylphosphino)pyridine 在 Me₃NO*H₂O 作用下， 以 乙醇 为溶剂， 以83%的产率得到(.+-.)-Fe(CO)4(2-(ethylphenylphosphino)pyridine-P)
  参考文献：
  名称：

  Formation of donor–acceptor Fe(0)–Hg(II) bond in separation and stabilization of optically active iron(0) phosphine complexes. Absolute configuration of (+)-(R)-(CO)4Fe(μ-EtPhPpy)HgCl2

  摘要：

  The chiral phosphine ligand 2-(ethylphenylphosphino)pyridine (EtPhPpy, R/S mixture) reacts with Fe(CO)(5) to give racemic (+/-)-Fe(CO)(4)(EtPhPpy-P), which undergoes an addition reaction with HgCl2 to afford the optically active binuclear Fe(0)-Hg(II) complexes (+)-(R)-(CO)(4)Fe(mu-EtPhPpy)HgCl2 and (-)-(S)-(CO)(4)Fe(mu-EtPhPpy)HgCl2, which can be separated manually in crystalline form. The absolute configuration of (+)-(R)-(CO)(4)Fe(mu-EtPhPpy)HgCl2 has been determined by single crystal X-ray analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00216-9