作者:V. A. Efremov、V. N. Potolokov、S. V. Nikolashin、V. A. Fedorov
DOI:10.1023/a:1019791114256
日期:——
The interaction of water with GeCl4, SnCl4, and AsCl3 was studied by IR spectroscopy. The results demonstrate that these chlorides contain molecular water in monomeric form. At water concentrations above 10(-2) mol/l, GeCl4 also contains H3O+ ions, The mechanisms of GeCl4 and AsCl3 hydrolysis were studied over a wide range of water concentrations.