trans-Fe(CO)3(Ph2Ptaz)2 | 223527-10-4

• 英文名称: trans-Fe(CO)3(Ph2Ptaz)2
• 英文别名: trans-Fe(CO)3(2-(diphenylphoshino)thiazole)2
• CAS: 223527-10-4
• 化学式: C₃₃H₂₄FeN₂O₃P₂S₂
• 分子量: 678.492
• InChiKey: PYBRLFIVTMGOBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-Fe(CO)3(Ph2Ptaz)2 、 mercury(II) thiocyanate 以 二氯甲烷 为溶剂， 以74%的产率得到trans-Fe(CO)3(2-(diphenylphoshino)thiazole)2Hg(SCN)2
  参考文献：
  名称：

  Directional Fe–CO⋯S intermolecular interaction leading to chain-like crystal packing in binuclear Fe(0)–M(II) (M=Hg, Cd) complexes with 2-(diphenylphosphino)thiazole

  摘要：

  A new thiazole-based phosphine ligand was designed to construct heterobinuclear complexes (CO)(3)Fe(mu-Ph2PNS)(2)MX2 (M = Hg, X = SCN; M = Cd, X = I; Ph2PNS = 2-(diphenylphosphino)thiazole), in which weak Fe-C=O ... S intermolecular interaction led to chain-like molecular packing in the solid state. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00952-8
• 作为产物：
  描述：

  五羰基铁 、 2-(diphenylphosphino)thiazole 在 NaOH 作用下， 以 正丁醇 为溶剂， 以70%的产率得到trans-Fe(CO)3(Ph2Ptaz)2
  参考文献：
  名称：

  Directional Fe–CO⋯S intermolecular interaction leading to chain-like crystal packing in binuclear Fe(0)–M(II) (M=Hg, Cd) complexes with 2-(diphenylphosphino)thiazole

  摘要：

  A new thiazole-based phosphine ligand was designed to construct heterobinuclear complexes (CO)(3)Fe(mu-Ph2PNS)(2)MX2 (M = Hg, X = SCN; M = Cd, X = I; Ph2PNS = 2-(diphenylphosphino)thiazole), in which weak Fe-C=O ... S intermolecular interaction led to chain-like molecular packing in the solid state. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00952-8

文献信息

• Reaction of 2-(diphenylphosphino)-pyridine and -thiazole organoiron(0) polydentate ligands with iron(III) salts
  作者：Shan-Ming Kuang、Zheng-Zhi Zhang、Feng Xue、Thomas C.W Mak

  DOI：10.1016/s0277-5387(99)00256-9

  日期：1999.11

  The reaction of trans-Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2) (Ph(2)Ppy=2-(diphenyhhosphino)pyridine) with FeCl3 resulted in the formation of the binuclear complex [eta(2)-Ph2P(O)py](2)Fe(mu-Cl)(2)FeCl2 (1), while the reaction of trans-Fe(CO)(3) (Ph(2)Ptaz-P)(2) (Ph(2)Ptaz=2-(diphenylphosphino)thiazole) with Fe(NCS)(3) gave Fe(NCS)(2)[eta(2)-Ph2P(O)taz](2) (2). The crystal structures of (1) and (2)C6H6 have been determined using X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.