1-硫代-b-甲基葡萄糖甙-4-甲基苯酯 | 1152-39-2

物质功能分类

医药中间体 - 吡喃类化合物

分子结构分类

有机化合物 - 有机氧化合物

中文名称

1-硫代-b-甲基葡萄糖甙-4-甲基苯酯

中文别名

对甲苯基-β-D-硫代吡喃葡萄糖苷；4-甲基苯基Β-D-硫代吡喃葡萄糖苷

英文名称

p-methylphenyl 1-thio-β-D-glucopyranoside

英文别名

p-tolyl 1-thio-β-D-glucopyranoside；4-methylphenyl 1-thio-β-D-glucopyranoside；4-Methylphenyl 1-thio-beta-D-glucopyranoside；(2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-(4-methylphenyl)sulfanyloxane-3,4,5-triol

CAS

1152-39-2

化学式

C₁₃H₁₈O₅S

mdl

——

分子量

286.349

InChiKey

IQCLIQLFPVKINX-LBELIVKGSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

0.7
重原子数：

19
可旋转键数：

3
环数：

2.0
sp3杂化的碳原子比例：

0.54
拓扑面积：

115
氢给体数：

4
氢受体数：

6

安全信息

WGK Germany：

3
危险性防范说明：

P261,P264,P271,P280,P302+P352,P304+P340,P305+P351+P338,P312,P362,P403+P233,P501
危险性描述：

H315,H319,H335
储存条件：

存储条件：2-8°C，密封于干燥处。

SDS

SDS：36b0b91e8bfcc21d554c98a8b0228fa4

查看

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
4-甲基苯基2,3,4,6-四-O-乙酰基-1-硫代吡喃己糖苷	4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside	28244-99-7	C₂₁H₂₆O₉S	454.498
——	p-tolyl-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside	——	C₂₁H₂₆O₉S	454.498
——	β-1-p-tolylthio-6-O-trityl-D-glucopyranose	819814-42-1	C₃₂H₃₂O₅S	528.669
1-吖丁啶羧酸,3-[(2-溴苯基)磺酰]-,1,1-二甲基乙基酯	1-thio-β-D-glucopyranose	7534-35-2	C₆H₁₂O₅S	196.224
1-硫代-b-D-葡萄糖四乙酸酯	tetraacetyl thioglucose	19879-84-6	C₁₄H₂₀O₉S	364.373

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	4-methylphenyl 4,6-O-isopropylidene-1-thio-β-D-glucopyranoside	——	C₁₆H₂₂O₅S	326.414
——	(2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-(4-methylphenyl)sulfanyl-3-phenylmethoxy-5-propan-2-yloxyoxan-4-ol	862851-27-2	C₂₃H₃₀O₅S	418.554
——	p-tolyl-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside	——	C₂₁H₂₆O₉S	454.498
——	p-tolyl 2,3-di-O-benzyl-1-thio-β-D-glucopyranoside	596087-18-2	C₂₇H₃₀O₅S	466.598
——	p-tolyl 3,6-O-bis(tert-butyldimethylsilyl)-1-thio-β-D-glucopyranoside	794521-00-9	C₂₅H₄₆O₅SSi₂	514.874
4,6-邻亚苄基-1-硫代-b-甲基葡萄糖甙-4-甲基苯酯	(p-methylphenyl) 4,6-O-benzylidene-1-thio-β-D-glucopyranoside	868241-49-0	C₂₀H₂₂O₅S	374.458
——	4-methylphenyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside	219518-19-1	C₂₀H₂₂O₅S	374.458
——	((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol	479252-05-6	C₃₄H₃₆O₅S	556.723
——	p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside	131531-76-5	C₄₁H₄₂O₅S	646.847
4-甲基苯基1-硫代-2,3,4,6-四-O-(三甲基硅烷基)-beta-D-吡喃葡萄糖苷	p-methylphenyl 2,3,4,6-tri-O-methylsilyl-1-thio-β-D-glucopyranoside	942043-17-6	C₂₅H₅₀O₅SSi₄	575.077
——	β-1-p-tolylthio-6-O-trityl-D-glucopyranose	819814-42-1	C₃₂H₃₂O₅S	528.669
——	p-tolyl 3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside	——	C₂₇H₂₈O₅S	464.582
——	4-methylphenyl (S)-6-O-[(4-methoxyphenyl)methyl]-2,3-bis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside	582322-06-3	C₃₅H₃₈O₆S	586.749
——	4-methylphenyl (S)-4,6-O-[(4-methoxyphenyl)methylene]-1-thio-β-D-glucopyranoside	582322-04-1	C₂₁H₂₄O₆S	404.484
——	4-methylphenyl 4,6-O-benzylidene-3-O-(methoxyethanoyl)-1-thio-β-D-glucopyranoside	219518-33-9	C₂₃H₂₆O₇S	446.521
——	p-methylphenyl-2,3,4,6-tetra-O-tert-butyldimethylsilyl-1-thio-β-D-glucopyranoside	178181-79-8	C₃₇H₇₄O₅SSi₄	743.4
4-甲基-2,3-双-O-(苯基甲基)-4,6-O-[(R)-苯基亚甲基]-1-硫代-β-D-吡喃葡萄糖苷苯酯	p-tolyl 2,3-di-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside	850416-39-6	C₃₄H₃₄O₅S	554.707
——	p=methylphenyl 2,3,6-tri-O-benzoyl-1-thio-β-D-glucopyranoside	220645-08-9	C₃₄H₃₀O₈S	598.673
——	p-tolyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside	762287-64-9	C₃₄H₃₀O₈S	598.673
——	p-tolyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside	172847-85-7	C₄₁H₃₄O₉S	702.782
——	p-tolyl-2,3,4-tri-O-benzyl-6-O-trityl-1-thio-β-D-glucopyranoside	762287-68-3	C₅₃H₅₀O₅S	799.043
——	2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-p-tolyl-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside	762287-73-0	C₆₈H₇₀O₁₀S	1079.36
——	p-tolyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside	854930-27-1	C₆₈H₇₀O₁₀S	1079.36
——	4-methylphenyl (S)-4,6-O-[(4-methoxyphenyl)methylene]-2,3-bis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside	582322-05-2	C₃₅H₃₆O₆S	584.733
——	methyl (2S,3S,4S,5R,6S)-3-hydroxy-6-(4-methylphenyl)sulfanyl-4,5-bis(phenylmethoxy)oxane-2-carboxylate	1352561-81-9	C₂₈H₃₀O₆S	494.609
——	p-tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside	942043-30-3	C₃₄H₃₂O₆S	568.69
4-甲基苯基4,6-O-苄叉-2,3-二-O-苯甲酰基-1-硫代-β-D-吡喃葡萄糖苷	p-methylphenyl 4,6-O-benzylidene-2,3-di-O-benzoyl-1-thio-β-D-glucopyranoside	323195-40-0	C₃₄H₃₀O₇S	582.674
——	p-tolyl-2,3,4-tri-O-benzoyl-6-O-trityl-1-thio-β-D-glucopyranoside	762287-69-4	C₅₃H₄₄O₈S	840.994
——	p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-1-deoxy-1-thio-β-D-glucopyranoside	——	C₆₈H₆₄O₁₃S	1121.31
——	p-methylphenyl 2,3-di-O-benzoyl-4-O-tert-butyldimethylsilyl-1-thio-β-D-glucopyranoside	727991-07-3	C₃₃H₄₀O₇SSi	608.828
——	p-tolyl 2-O-benzoyl-3-O-benzyl-4-O-tert-butyldimethylsilyl-6-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside	929040-56-2	C₄₁H₅₀O₇SSi	714.995
——	p-tolyl 2,3,4-tri-O-benzyl-6-O-t-butyldiphenylsilyl-1-thio-β-D-glucopyranoside	807361-70-2	C₅₀H₅₄O₅SSi	795.127

反应信息

作为反应物：

描述：