Erbium;nickel | 12159-67-0

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间镧系化合物
• 英文名称: Erbium;nickel
• 英文别名: erbium;nickel
• CAS: 12159-67-0
• 化学式: Er₃Ni
• 分子量: 560.47
• InChiKey: NRGKZXZYYYCXCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.0
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Erbium;nickel 、 氢气 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Metal–semiconductor–insulator transitions in R3Ni compounds induced by hydrogenation

  摘要：

  Electrical resistivity and ac magnetic susceptibility measurements of R3Ni and their hydrides R3NiHx were carried out. It is shown that the conductivity of R3NiHx compounds with a large amount of hydrogen have semiconductor and insulator conductivity type as compared with metallic conduction in the original compounds R3Ni. The resistivity of the original compounds is discussed on the basis of a conduction electron scattering model. Strongly modified transport processes of the hydrides are discussed on basis of a 'hopping' model. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)01238-x
• 作为产物：
  描述：

  镍 、 氢化铒 以 melt 为溶剂， 生成 Erbium;nickel
  参考文献：
  名称：

  Ternary system Er–Ni–In at T=870K

  摘要：

  Isothermal section of the Er-Ni-In system at T=870 K was constructed by means of X-ray powder diffraction and EDX-analyses. Nine ternary compounds, namely ErNi9In2 (YNi9In2-type), Er1-1.22NI4In1-0.78 (MgCu4Sn-type), Er10Ni9.07In20 (Ho10Ni9In20-type), ErNi1-0.60In1-1.40 (ZrNiAl-type), Er2Ni2In (Mn(2)AIB(2)-type), Er2Ni1.78In (Mo2FeB2-type), Er5Ni2In4 (Lu5Ni2In4-type), Er5Ni2In (Mo5SiB2-type), and Er13.53Ni3.14In3.33 (Lu14Co2In3-type), exist in the Er-Ni-In system at this temperature. The substitution of Ni for In was observed for ErNi1-0.60In1-1.40 and In for Er in the case of related compounds ErNi2 and ErNi4In. Er can enter NiIn (CoSn-type) leading to including-substitution type of compound Er0-0.12NiIn1-0.89. Basic magnetic properties of the Er0.04NiIn0.97, ErNi2, Er0.9Ni2In0.1, and ErNi4In phases were inspected. Electrical-resistivity studies were performed on the ErNiIn, ErNi0.9In1.1, and ErNi4In phases. (C) 2011 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2011.08.006

文献信息

• The isothermal section of the Er–Mn–Ni ternary system at 803 K
  作者：Jingqi Liu、Fangwei Jiao、Yinghong Zhuang、Fengquan Ma、Zhihui Sun

  DOI：10.1016/j.jallcom.2004.04.086

  日期：2004.12

  The isothermal section of the phase diagram of the Er-Mn-Ni ternary system at 803 K was investigated by X-ray powder diffraction with the aid of microanalysis and electron probe microanalysis techniques. It consists of 14 single-phase regions, 24 two-phase regions, and 11 three-phase regions. At 803 K, the maximum solid solubility of Mn in Ni, Er2Ni17,ErNi5,Er2Ni7,ErNi3, and ErNi2 is about 31, 13, 8,4, 3, and 2 at.% Mn, respectively. The maximum solid solubility of Ni in Mn, ErMn12, and Er6Mn23 is about 3 at.% Ni, for all three compounds. The existence of ErNi4, Er4Ni17, and Er5Ni22 has not been confirmed. The existence of any ternary compound of the Er-Mn-Ni was not observed. (C) 2004 Elsevier B.V. All rights reserved.
• The 773 K isothermal section of Er–Ni–Sb phase diagram
  作者：Lingmin Zeng、Lizhen Tan

  DOI：10.1016/s0925-8388(02)00522-4

  日期：2002.11

  The isothermal section of the Er-Ni-Sb ternary system at 773 K has been investigated mainly by X-ray powder diffraction with the aid of differential thermal analysis and scanning electron microscopy. The formation of the previously reported ErNiSb and Er5Ni2Sb, was confirmed. No new ternary compounds were observed. (C) 2002 Elsevier Science B.V. All rights reserved.
• Ternary system Er–Ni–In at T=870K
  作者：M. Dzevenko、Yu. Tyvanchuk、L. Bratash、V. Zaremba、L. Havela、Ya. Kalychak

  DOI：10.1016/j.jssc.2011.08.006

  日期：2011.10

  Isothermal section of the Er-Ni-In system at T=870 K was constructed by means of X-ray powder diffraction and EDX-analyses. Nine ternary compounds, namely ErNi9In2 (YNi9In2-type), Er1-1.22NI4In1-0.78 (MgCu4Sn-type), Er10Ni9.07In20 (Ho10Ni9In20-type), ErNi1-0.60In1-1.40 (ZrNiAl-type), Er2Ni2In (Mn(2)AIB(2)-type), Er2Ni1.78In (Mo2FeB2-type), Er5Ni2In4 (Lu5Ni2In4-type), Er5Ni2In (Mo5SiB2-type), and Er13.53Ni3.14In3.33 (Lu14Co2In3-type), exist in the Er-Ni-In system at this temperature. The substitution of Ni for In was observed for ErNi1-0.60In1-1.40 and In for Er in the case of related compounds ErNi2 and ErNi4In. Er can enter NiIn (CoSn-type) leading to including-substitution type of compound Er0-0.12NiIn1-0.89. Basic magnetic properties of the Er0.04NiIn0.97, ErNi2, Er0.9Ni2In0.1, and ErNi4In phases were inspected. Electrical-resistivity studies were performed on the ErNiIn, ErNi0.9In1.1, and ErNi4In phases. (C) 2011 Elsevier Inc. All rights reserved.
• Incoherent rotation of the erbium magnetic moments during magnetization processes of the Er3Ni and Er3Co compounds
  作者：N.V Tristan、S.A Nikitin、T Palewski、K Skokov

  DOI：10.1016/s0304-8853(02)00492-4

  日期：2002.10

  The investigations of magnetization processes for Er3Ni and Er3CO single crystal compounds are presented. The magnetization processes are discussed on the basis of magnetic structures determined previously by neutron diffraction for both compounds. It is shown that both ferromagnetic and antiferromagnetic exchange interactions as well as strong local ionic anisotropy of erbium atoms play a significant role in the magnetization processes forming. (C) 2002 Elsevier Science B.V. All rights reserved.
• Rare-earth-rich tellurides: Gd4NiTe2 and Er5M2Te2 (M=Co, Ni)
  作者：Carmela Magliocchi、Fanqin Meng、Timothy Hughbanks

  DOI：10.1016/j.jssc.2004.07.019

  日期：2004.11

  Three new rare earth metal-rich compounds, Gd4NiTe2, and Er5M2Te2 (M = Ni, Co), were synthesized in direct reactions using R, R3M, and R2Te3 (R = Gd, Er; M = Co, Ni) and single-crystal structures were determined. Gd4NiTe2 is orthorhombic and crystallizes in space group Pnma with four formula units per cell. Lattice parameters at 110(2) K are a = 15.548(9), b = 4.113(2), c = 11.7521(15) Angstrom Er5Ni2Te2 and Er5Co2Te2 are isostructural and crystallize in the orthorhombic space group Cmcm with two formula units per cell.. Lattice parameters at 110(2) K are a = 3.934(l), b = 14.811(4), c = 14.709(4) Angstrom, and a = 3.898(1), b = 14.920(3), c = 14.889(3) Angstrom, respectively. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept. Angstrom 2004 Elsevier Inc. All rights reserved.