[Re(CO)3Br((4-chlorophenyl)pyridin-2-ylmethyleneamine)] | 1268280-78-9

• 英文名称: [Re(CO)3Br((4-chlorophenyl)pyridin-2-ylmethyleneamine)]
• CAS: 1268280-78-9
• 化学式: C₁₅H₉BrClN₂O₃Re
• 分子量: 566.812
• InChiKey: JDBDBAATEIGITE-GNWKECPVSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(pyrid-2-ylmethylene)-p-chlorophenylamine 、 五羰基溴铼(I) 以 氘代甲苯 为溶剂， 以91%的产率得到[Re(CO)3Br((4-chlorophenyl)pyridin-2-ylmethyleneamine)]
  参考文献：
  名称：

  Tricarbonylrhenium(I) Bromide Complexes With Diimine Ligands: Structural, Electrochemical, and Spectroscopic Studies

  摘要：

  Four rhenium(I) complexes, [Re(CO)(3)Br(L-n)] (n = 1-4), [L-n = (4-fluorophenyl)pyridin-2-ylmethyleneamine (L-1), (4-chlorophe nyl)pyridin-2-ylmethyleneamine (L-2), (4-bromophenyl)pyridin-2-ylmethyleneamine (L-3), and (4-iodophenyl)pyridin-2-ylmethyleneamine, (L-4)] have been synthesized and characterized by CHN analyses, H-1, C-13-NMR, IR, and UV-vis spectroscopy. The molecular structure of [Re(CO)(3)Br(L-1)] is a distorted octahedron around rhenium with one Br, facial arrangement of three COs, and one diimine. UV-vis absorption and emission properties of the complexes have been studied at room temperature and the redox potentials are approximately insensitive to the substituent on the phenyl ring of ligands.

  DOI：

  10.1080/15533174.2012.680160