| 154626-52-5

• CAS: 154626-52-5
• 化学式: C₁₆H₁₆Cl₂N₂O₄Sn
• 分子量: 489.93
• InChiKey: WQVMFNJZOCQOFK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 硫氰酸酯 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and reactivity of bis-4-pyrone and bis-4-pyridinone dichlorotin(IV) compounds

  摘要：

  A number of tin(IV) complexes, Sn(LL)2X2, have been prepared in which LL is a 4-pyronate or 4-pyridinonate ligand and X is chloride or alkoxide. UV-vis, IR and NMR (H-1, C-13, Sn-119) spectra are reported for these complexes. Reactivities have been established through kinetic studies of nucleophilic substitution in acetonitrile solution. Ligand effects on spectra and reactivity are discussed and compared with those for similar metal(IV) complexes, especially of titanium.

  DOI：

  10.1016/s0277-5387(00)81466-7
• 作为产物：
  描述：

  N-羟基-4-甲基苯甲酰胺 、 四氯化锡 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and reactivity of bis-4-pyrone and bis-4-pyridinone dichlorotin(IV) compounds

  摘要：

  A number of tin(IV) complexes, Sn(LL)2X2, have been prepared in which LL is a 4-pyronate or 4-pyridinonate ligand and X is chloride or alkoxide. UV-vis, IR and NMR (H-1, C-13, Sn-119) spectra are reported for these complexes. Reactivities have been established through kinetic studies of nucleophilic substitution in acetonitrile solution. Ligand effects on spectra and reactivity are discussed and compared with those for similar metal(IV) complexes, especially of titanium.

  DOI：

  10.1016/s0277-5387(00)81466-7