[Ru(η3:η3-C10H16)Cl2(κ1-P-Ph2P(CH2)4P(=O)Ph2)] | 623172-42-9

• 英文名称: [Ru(η3:η3-C10H16)Cl2(κ1-P-Ph2P(CH2)4P(=O)Ph2)]
• CAS: 623172-42-9
• 化学式: C₃₈H₄₄Cl₂OP₂Ru
• 分子量: 750.69
• InChiKey: RMMLYESWAWZGBB-VPACTKIZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ru(η3:η3-C10H16)(μ-Cl)Cl]2 、 [4-(二苯基膦)丁基]二苯基氧化膦 以 二氯甲烷 为溶剂， 以96%的产率得到[Ru(η3:η3-C10H16)Cl2(κ1-P-Ph2P(CH2)4P(=O)Ph2)]
  参考文献：
  名称：

  Reactivity of the dimer [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] towards diphosphines and diphosphine-monoxides: synthesis and characterization of novel (2,7-dimethylocta-2,6-diene-1,8-diyl)-ruthenium(IV) complexes

  摘要：

  Treatment of complex [Ru(eta(3):eta(3)-C-10 H-16)Cl-2(kappa(1)-P-Ph2PCH2PPh2)] (2) with AgBF4 yields the chelate derivative [Ru(eta(3):eta(3)- C10H16)Cl(kappa(2)-P, P-Ph2PCH2PPh2)][BF4] (3). Attempts to generate species structurally related to 2 by reaction of the bis(allyl)-ruthenium(IV) dimer (1) with diphosphines Ph2P(CH2)(n)PPh2 (n = 2, 3, 4) failed, obtaining instead the dinuclear compounds [{Ru{eta(3):eta(3)-C10H16)Cl-2}(2){mu-Ph2P(CH2)(n) PPh2}] (n = 2 (4a), 3 (4b), 4 (4c)). In contrast, mononuclear neutral species [Ru(eta(3):eta(3)-C10H16)Cl-2{kappa(1)-P-Ph2P(CH2)(n) P(=O)Ph-2] (n = 1 (5a), 2 (5b), 3 (5c), 4 (5d)) have been easily prepared by reaction of 1 with the corresponding diphosphine-monoxide Ph2P(CH2)(n) P(-O)Ph-2 (n = 1, 2, 3, 4). Treatinent of 5a,b with AgBF4 allows the formation of cationic derivatives [Ru(eta(3):eta(3)-C10H16)Cl {kappa(2)-P, O-Ph2P(CH2)(n) P(-O)Ph-2}][BF4] (n = 1 (6a), 2 (6b)). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01437-8