(diphenylphosphino-3-pyridylcarbinol) tetrafluoroborate | 664980-67-0

• 英文名称: (diphenylphosphino-3-pyridylcarbinol) tetrafluoroborate
• CAS: 664980-67-0
• 化学式: Ag*BF₄*C₁₈H₁₆NOP
• 分子量: 487.978
• InChiKey: UJYORGSIRJSYBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (diphenylphosphino-3-pyridylcarbinol) tetrafluoroborate 以 not given 为溶剂， 生成 银
  参考文献：
  名称：

  Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh₂(3-OCH₂C₅H₄N)

  摘要：

  The novel phosphinite PPh2(3-OCH2C5H4N) (1) has been synthesized, and its coordination properties to Ag(I) have been studied. When reacted in a 1:1 ratio with Ag(l), coordination polymers with different coordination numbers about the Ag are found depending on the anion. For PPh2(3-OCH2C5H4N)AgBF4 (2), a two-coordinate Ag is observed with a P-Ag-N angle of 167degrees. Mixed three and four coordination about Ag is observed for PPh2(3-OCH2C5H4N)-AgOTf (3), and for the trifluoroacetate derivative, PPh2(3-OCH2C5H4N)Agtfa (4), only a four-coordinate Ag is produced. X-ray crystal-structure determinations for compounds 2-4 have been carried out. The X-ray structures show a wide range of Ag-Ag distances in the polymers, which are dependent on the conformation of the bridging ligand.

  DOI：

  10.1021/ic035168a
• 作为产物：
  描述：

  diphenylphosphino-3-pyridylcarbinol 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以91%的产率得到(diphenylphosphino-3-pyridylcarbinol) tetrafluoroborate
  参考文献：
  名称：

  Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh₂(3-OCH₂C₅H₄N)

  摘要：

  The novel phosphinite PPh2(3-OCH2C5H4N) (1) has been synthesized, and its coordination properties to Ag(I) have been studied. When reacted in a 1:1 ratio with Ag(l), coordination polymers with different coordination numbers about the Ag are found depending on the anion. For PPh2(3-OCH2C5H4N)AgBF4 (2), a two-coordinate Ag is observed with a P-Ag-N angle of 167degrees. Mixed three and four coordination about Ag is observed for PPh2(3-OCH2C5H4N)-AgOTf (3), and for the trifluoroacetate derivative, PPh2(3-OCH2C5H4N)Agtfa (4), only a four-coordinate Ag is produced. X-ray crystal-structure determinations for compounds 2-4 have been carried out. The X-ray structures show a wide range of Ag-Ag distances in the polymers, which are dependent on the conformation of the bridging ligand.

  DOI：

  10.1021/ic035168a