| 400033-80-9

• CAS: 400033-80-9
• 化学式: C₁₇H₁₅ClN₂Pd
• 分子量: 389.192
• InChiKey: OXVCDZZSQRNIGA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 solid 为溶剂， 生成 碳酸甲丙酯 、 di-μ-chlorobis{(2-phenylpyridine)palladium(II)}
  参考文献：
  名称：

  摘要：

  The complex [Pd(2-Phpy)(mu -Cl)](2) reacts with pyridines (L=pyridine, alpha -picoline and gamma -picoline), amines (L=isopropylamine, tert-butylamine) and ammonia to form the corresponding ortho-palladated derivatives [Pd(2-Phpy)ClL]. The compounds have been characterized by C, H and N analyses and spectroscopic methods (IR and H-1 and C-13 NMR). TG, DTG and DSC studies of the complexes were carried out in dynamic nitrogen atmosphere, From DSC analyses the heats of decomposition were calculated. The kinetics of the first step of thermal decomposition were evaluated from TG data by isothermal methods for L=pyridine and isopropylamine. The activation energies obtained are in the range 90-100 kJ mol(-1). The best fitting for data was observed for R2 and A1.5 kinetic models.

  DOI：

  10.1023/a:1013118929427
• 作为产物：
  描述：

  2-苯基吡啶 以 乙醇 、 水 、 丙酮 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Structural and 1H, 13C, 15N NMR spectroscopic studies of Pd(II) chloride organometallics with 2-phenylpyridine and ammonia, pyridine or its methyl derivatives

  摘要：

  Pd(II) chloride organometallics with 2-phenylpyridine and pyridines of general formula [Pd(2ppy*)LCl] (2ppy* = C(2')-deprotonated form of 2-phenylpyridine (2ppy), acting as N(1),C(2')-chelating ligand; L = NH3, pyridine, 2-, 3-, 4-methylpyridine, 2,3-, 2,4-, 2,6-, 3,5-dimethylpyridine, 2,4,6-trimethylpyridine) were studied by H-1, C-13 and N-15 NMR. H-1, C-13 and N-15 NMR coordination shifts (i.e. differences of chemical shifts for the same atom in the complex and ligand molecules) were discussed in relation to the molecular structures. Single crystal X-ray structure of trans(N,N)-[Pd(2ppy*)(2,4,6col)Cl] was solved. The analysis of 15N NMR coordination shifts for the whole series of the studied organometallics exhibited that all of them had an analogous trans(N,N) geometry. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.02.028