mer-carbonyl-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)-[(Z)-1-phenylethinyl-2-phenylethenyl]-trans-bis(trimethylphosphine)cobalt(III) | 905917-66-0

• 英文名称: mer-carbonyl-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)-[(Z)-1-phenylethinyl-2-phenylethenyl]-trans-bis(trimethylphosphine)cobalt(III)
• CAS: 905917-66-0
• 化学式: C₃₈H₃₉CoO₃P₂
• 分子量: 664.667
• InChiKey: NGVXRZPEBAFFOA-TWPNBRPISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1-carbonyl-2-oxo-1,2-diphenylethenediyl)-[(Z)-1-phenylethinyl-2-phenylethenyl]-trans-bis(trimethylphosphine)cobalt(III) 、 一氧化碳 以 乙醚 为溶剂， 以37%的产率得到mer-carbonyl-(1-carbonyl-2-oxo-1,2-diphenylethenediyl)-[(Z)-1-phenylethinyl-2-phenylethenyl]-trans-bis(trimethylphosphine)cobalt(III)
  参考文献：
  名称：

  Novel stable five-coordinate diorgano cobalt(III) complexes: Formation, structure, and reaction with carbon monoxide

  摘要：

  A series of new five-coordinate acyl vinyl cobalt(III) complexes Co{eta(1)-C(C CPh)=CHPh}[C(O)-C=C-O]L-2(L=PMe3) (6-10) were prepared via formal insertion of diphenylbutadiyne into Co-H function of mer-octahedral hydrido-acyl(phenolato)-cobalt(III) complexes. The complexes are diamagnetic. One square pyramidal structure of complex 6 was confirmed by X-ray diffraction analysis. These complexes are stable in solid state. In solution, six-coordinate acyl vinyl carbonyl cobalt(III) complex 11 is approved through the reaction of complex 7 with CO and the structure of complex 11 was determined by X-ray method. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.029