(p-cymene)RuI₂(2,6-diethylphenyl isocyanide) | 1469885-79-7

• 英文名称: (p-cymene)RuI₂(2,6-diethylphenyl isocyanide)
• CAS: 1469885-79-7
• 化学式: C₂₁H₂₇I₂NRu
• 分子量: 648.331
• InChiKey: JEYHSFPETVCCCE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  diiodo(p-cymene)ruthenium(II) dimer 、 2,6-二乙基苯基异腈 以 二氯甲烷 为溶剂， 以93%的产率得到(p-cymene)RuI₂(2,6-diethylphenyl isocyanide)
  参考文献：
  名称：

  Synthesis and characterization of a series of rhodium, iridium, and ruthenium isocyanide complexes

  摘要：

  Several new electrophilic metal isocyanide complexes have been fully characterized and reported herein. Isocyanide induced cleavage of the dimer, [LMCl2](2) {LM = Cp*Ir, Cp*Rh, or (p-cymene)Ru}, with 2, 6-xylylisocyanide or 2,6-diethylphenylisocyanide produces complexes of the general formula LM(CNAr)Cl-2. Halide metathesis of the dichloro complexes with sodium iodide produces the corresponding complexes with the general formula LM(CNAr)I-2. For the analogous ruthenium complexes better results were achieved via isocyanide induced cleavage of [(p-cymene)RuI2](2) and was synthesized differently from previous reports. Several neutral complexes in reaction with AgPF6 in acetonitrile form cationic, solvent-coordinated complexes have been fully characterized. Most reactions with rhodium decomposed to either [Cp*RhCl(MeCN)](2)[(PF6)(2)] starting from the dichloro complexes, or [Cp*Rh(MeCN)(3),(PF6)(2)] and Cp*Rh(CNAr)I-2 starting from the diiodo complexes. Several bases were probed to see if cyclization could be induced, but were not successful in any case. Many of these complexes have been characterized by single crystal X-ray crystallography. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.07.039