(η(5)-2,4-cyclopentadien-1-yl)[methyl (5a,6,7,8,9,9a-η)-6-N,N-dimethylaminodibenzo[b,e][1,4]dioxin-1-carboxylate]ruthenium hexafluorophosphate | 174499-60-6

• 英文名称: (η(5)-2,4-cyclopentadien-1-yl)[methyl (5a,6,7,8,9,9a-η)-6-N,N-dimethylaminodibenzo[b,e][1,4]dioxin-1-carboxylate]ruthenium hexafluorophosphate
• CAS: 174499-60-6
• 化学式: C₂₁H₂₀NO₄Ru*F₆P
• 分子量: 596.428
• InChiKey: CIIUXXFESATGCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 2,3-二羟基苯甲酸甲酯 、 (η(5)-2,4-cyclopentadien-1-yl)(η(6)-N,N-dimethyl-2,3-dichlorobenzenamine)ruthenium hexafluorophosphate 在 K₂CO₃ 、 HCl 作用下， 以 四氢呋喃 、 水 为溶剂， 以23%的产率得到(η(5)-2,4-cyclopentadien-1-yl)[methyl (5a,6,7,8,9,9a-η)-6-N,N-dimethylaminodibenzo[b,e][1,4]dioxin-1-carboxylate]ruthenium hexafluorophosphate
  参考文献：
  名称：

  Towards the synthesis of amino[b,e][1,4]dioxin derivatives via cationic ruthenium complexes

  摘要：

  Double nucleophilic aromatic substitution reactions between N-substituted (eta(6)-1,2-dichlorobenzene)RuCp(+) salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare N-substituted (eta(6)-dibenzo[b,e][1,4]dioxin)ruthenium(II) complexes. The dibenzodioxin ligands were subsequently liberated by photolysis, with radiation from a sunlamp or from a medium pressure Hg lamp (300 nm).

  DOI：

  10.1016/0022-328x(95)05717-4