[Pt(1,2-benzenediol(-2H))(cod)] | 181819-84-1

• 英文名称: [Pt(1,2-benzenediol(-2H))(cod)]
• CAS: 181819-84-1
• 化学式: C₁₄H₁₆O₂Pt
• 分子量: 411.36
• InChiKey: MRYBELRIOMPOJQ-GCOBPYNFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 邻苯二酚 在 KOH 作用下， 以 甲醇 为溶剂， 以64%的产率得到[Pt(1,2-benzenediol(-2H))(cod)]
  参考文献：
  名称：

  Base-promoted synthesis of monometallic and bimetallic platinum complexes containing chelating O,O- or S,S-donor ligands

  摘要：

  Dichloroplatinum complexes [PtCl2L2] (L-2 = cod, dppp) react with 1,2-C6H4E2 (E = O, S) in the presence of a base to produce mononuclear complexes The diene was not readily displaced from [Pt(E2C6H4-EE)(cod)]. A second approach to complexes containing dianionic chelating ligands involved [Pt(acac)2] as precursor. Reaction with dppp and oxalic acid gave [Pt(C2O4)(dppp)], whereas the analogous reaction with Ph2PC -CPPh2 produced the bimetallic complex [Pt(C2O4-OO)(mu-Ph2PC CPPh2)(2). Similar reactions with 1,2-C6H4E2 (E = O, S) also gave bimetallic products. The structures of [Pt(C2O4)(dppp)] and [Pt(C2O4-OO)(mu-Ph2PC CPPh2)](2) have been determined by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.060