[(η5-C5H4Hex)RuBr(cod)] | 623947-20-6

• 英文名称: [(η5-C5H4Hex)RuBr(cod)]
• CAS: 623947-20-6
• 化学式: C₁₉H₂₉BrRu
• 分子量: 438.413
• InChiKey: NQVOMPYZLYLROR-ONEVTFJLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η5-C5H4Hex)RuBr(cod)] 、 4,4'-二乙炔基联苯 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Poly(biphenylene ruthenacyclopentatrienylene), a New Organometallic Conducting Polymer with Ferromagnetic Interaction in Its Reduced State

  摘要：

  A ruthenacyclopentatriene polymer 2 was synthesized by metallacycling polymerization (MCP). Polymer 2 with Mn = 3400 and Mw = 5800 consisted of identical ruthenacyclopentatriene units. The UV-vis spectra of 2 showed a shift of the pi-pi* band to a longer wavelength due to the enlargement of the pi-conjugation. Polymer 2 underwent reversible reduction due to the ruthenacycle moiety at -1.01 V versus ferrocenium/ferrocene. The EPR spectrum of the reduced form of 2 in frozen THF indicated ferromagnetic interaction of spins at ruthenacyclopentatriene units.

  DOI：

  10.1021/ja036934f