trans-Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Te) | 250380-11-1

• 英文名称: trans-Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Te)
• CAS: 250380-11-1
• 化学式: C₁₈H₁₀Fe₂Mo₂O₈STe
• 分子量: 817.513
• InChiKey: OTAQPVNKUDWDMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetracarbonyldicyclopentadienyldimolybdenum 、 Fe2(CO)6(μ-STe)2 以 苯 为溶剂， 以18%的产率得到cis-Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Te)
  参考文献：
  名称：

  Synthesis and characterisation of cis and trans isomers of the mixed chalcogen clusters Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Se) and Cp2Mo2Fe2(CO)8(μ3-S)(μ3-Te)

  摘要：

  The reaction of Fe-2(CO)(6)(mu-SSe) and Cp2Mo2(CO)(4) in benzene at room temperature for 2 h, yielded the new isomeric mixed-metal, mixed-dichalcogenide clusters trans-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Se) (1) and cis-Cp2Mo2Fe2(Co)(8)(mu(3)-S)(mu(3)-Se) (4). The new mixed-metal clusters 1 and 4 could also be obtained when Fe-3(CO)(9)(mu(3)-S)(mu(3)-Se) and Cp2Mo2(CO)(6) were heated at 65 degrees C in benzene for 36 h. Similarly, the room-temperature reaction of Fe-2(CO)(6)(mu-STe) with Cp2Mo2(CO)(4) in benzene for 2 h and the thermolytic reaction of Fe-3(CO)(9)(mu(3)-S)(mu(3)-Te) with Cp2Mo2(CO)(6) in benzene for 36 h afforded the new isomeric clusters trans-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Te) (9) and cis-Cp2Mo2Fe2(CO)(8)(mu(3)-S)(mu(3)-Te) (11). The new clusters have been characterised by IR and by H-1-, Se-77-, Te-125-NMR spectroscopy. Clusters 1 and 4 have also been structurally characterised by single-crystal X-ray diffraction methods. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00285-5