[tetra(p-methoxyphenyl)porphyrinato]platinum(IV) dibromide | 288084-47-9

• 英文名称: [tetra(p-methoxyphenyl)porphyrinato]platinum(IV) dibromide
• CAS: 288084-47-9
• 化学式: C₄₈H₃₆Br₂N₄O₄Pt
• 分子量: 1087.73
• InChiKey: QCYBZTDFPQSKDR-KDTBAHQYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氢碘酸 、 [tetra(p-methoxyphenyl)porphyrinato]platinum(IV) dibromide 生成 (meso-tetra(parametoxyphenyl)porphin)Pt
  参考文献：
  名称：

  Platinum(IV) tetraphenylporphyrin dibromide complexes: synthesis, characterization, and electrochemistry

  摘要：

  Platinum(IV) porphyrins of the type [Pt-IV(p-X)(4)TPP]Br-2 where (p-X)(4)TPP is a para-substituted tetraphenylporphyrin have been synthesized by direct oxidation of their Pt(II) precursors with Br-2. Both the Pt(II) and Pt(IV) complexes have been characterized by visible and H-1 NMR spectroscopy and their electrochemical properties. In both the oxidation and reduction processes, a substituent effect is evident, and the reduction of Pt-IV-->Pt-II is identified. The oxidation and reduction potentials of the [ Pt-IV(p-X)(4)TPP] Br-2 complexes are compared to those of the [Pt-II(p-X)(4)TPP] precursors and [Pt-IV(p-X)(4)TPP]Cl-2 analogs. Addition of I-2 or I- to Pt(II) porphyrins does not result in oxidative-addition to form Pt(IV) porphyrins. Instead, the addition of I- to [Pt-IV(p-X)(4)TPP]Br-2 results in the reduction of the platinum to form the corresponding [Pt-II(p-X)(4)TPP)]. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00349-1
• 作为产物：
  描述：

  (meso-tetra(parametoxyphenyl)porphin)Pt 、 溴 以 氯仿 为溶剂， 以75%的产率得到[tetra(p-methoxyphenyl)porphyrinato]platinum(IV) dibromide
  参考文献：
  名称：

  Platinum(IV) tetraphenylporphyrin dibromide complexes: synthesis, characterization, and electrochemistry

  摘要：

  Platinum(IV) porphyrins of the type [Pt-IV(p-X)(4)TPP]Br-2 where (p-X)(4)TPP is a para-substituted tetraphenylporphyrin have been synthesized by direct oxidation of their Pt(II) precursors with Br-2. Both the Pt(II) and Pt(IV) complexes have been characterized by visible and H-1 NMR spectroscopy and their electrochemical properties. In both the oxidation and reduction processes, a substituent effect is evident, and the reduction of Pt-IV-->Pt-II is identified. The oxidation and reduction potentials of the [ Pt-IV(p-X)(4)TPP] Br-2 complexes are compared to those of the [Pt-II(p-X)(4)TPP] precursors and [Pt-IV(p-X)(4)TPP]Cl-2 analogs. Addition of I-2 or I- to Pt(II) porphyrins does not result in oxidative-addition to form Pt(IV) porphyrins. Instead, the addition of I- to [Pt-IV(p-X)(4)TPP]Br-2 results in the reduction of the platinum to form the corresponding [Pt-II(p-X)(4)TPP)]. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00349-1