| 640282-51-5

• CAS: 640282-51-5
• 化学式: C₃₄H₃₂Cl₂N₆P₂Pt
• 分子量: 852.602
• InChiKey: BIZPKXMVHSKLPS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 2-diphenylphosphinohydrazinopyridine 以 二氯甲烷 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Preparation and coordination chemistry of Ph2PNHNHpy

  摘要：

  Ph(2)PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(muCl)(eta(3)-C3H5)](2), [RhCl(cod)](2), [RuCl2(eta(3):eta(3)-Cl10H16)](2), [RuCl2(p-Cy)](2), [IrCp*Cl-2](2), and [Cu(MeCN)(4)][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph(2)PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(eta(3):eta(3)- C10H16)(Ph(2)PNHNHpy-P)] and [IrCp*Cl-2(Ph(2)PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00115-3