| 1283728-34-6

• CAS: 1283728-34-6
• 化学式: C₁₆H₁₁MoNO₅S₂
• 分子量: 457.339
• InChiKey: ZYNUVXNYLXSNRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-[(4,5-dimethyl-1,3-dithiol-2-ylidene)methyl]pyridine 、 molybdenum hexacarbonyl 以 甲苯 为溶剂， 以26%的产率得到
  参考文献：
  名称：

  Pyridyldithiafulvene as N-ligand towards molybdenum carbonyl complexes and evidence of protonation through hydrolysis of lead perchlorate

  摘要：

  The ability of pyridyldithiafulvenes to react as monodentate ligand with Mo(CO)(6) and Pb(ClO4)(2) has been investigated. The corresponding molybdenum carbonyl complexes have been isolated while no coordination to lead has been observed. As evidenced by X-ray crystal structure analysis, protonation of the pyridyl moiety has occurred due to the propensity of lead perchlorate trihydrate to hydrolyze in acetonitrile. The spectroscopic and redox properties of the molybdenum complexes as well as the pyridinium dithiafulvenes have been compared with their precursors and discussed. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.12.040