{hydrido(1,2-bis(dimethylphosphino)ethane)bis(η5-tetramethylphospholyl)uranium} | 155706-50-6

• 英文名称: {hydrido(1,2-bis(dimethylphosphino)ethane)bis(η5-tetramethylphospholyl)uranium}
• CAS: 155706-50-6
• 化学式: C₂₂H₄₁P₄U
• 分子量: 667.491
• InChiKey: YPBZBSUKRWFMAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {dimethylbis-(η5-tetramethylphospholyl)uranium} 、 1,2-双(二甲基瞵)乙烷 、 氢气 以 氘代苯 为溶剂， 生成 {hydrido(1,2-bis(dimethylphosphino)ethane)bis(η5-tetramethylphospholyl)uranium}
  参考文献：
  名称：

  Tetramethylphospholyluranium complexes and their pentamethylcyclopentadienyl analogues

  摘要：

  The mono- and bis-(tetramethylphospholyl)uranium complexes [U(tmp)(Cl)(3)(L)(2)] (tmp = C(4)Me(4)P, L = tetrahydrofuran or L(2) = dimethoxyethane), [U(tmp)(X)(3)] (X = BH4, CH(2)Ph) and [U(tmp)(2)(X)(2)] (X = Cl, BH4, alkyl, or alkoxide) were compared with their pentamethylcyclopentadienyl (cp*) analogues. The crystal structures of [U(tmp)(Cl)(3)(dimethoxyethane)] and [U(cp*)(2)(BH4)(2)] have been determined. Although the structures of the phospholyl compounds are similar to those of their cyclopentadienyl counterparts, the distinct electronic effects of the tmp and cp* ligands (tmp being less electron-donating than cp*) are manifest in the coordinating and redox properties of the complexes.

  DOI：

  10.1016/0022-328x(94)88035-2