[Et4N][Ga(SeC6H5)4] | 1194631-75-8

• 英文名称: [Et4N][Ga(SeC6H5)4]
• CAS: 1194631-75-8
• 化学式: C₈H₂₀N*C₂₄H₂₀GaSe₄
• 分子量: 824.239
• InChiKey: ORIDUZNQMQXWET-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium phenylselenide 、 Me₄N[Ga^IIICl4] 以 甲醇 为溶剂， 以63%的产率得到[Et4N][Ga(SeC6H5)4]
  参考文献：
  名称：

  Syntheses and crystal structures of the homoleptic [Et4N][M(SC6H4Me-p)4] (M=Ga, In) and [Et4N][Ga(SePh)4]

  摘要：

  Treatment of [Et4N][GaCl4] with four equivalents of NaQR in methanol afforded the substitution complexes [Et4N][Ga(QR)(4)] (QR = SC6H4Me-p 1, QR = SePh 3), while the indium analogues [Et4N][In(SC6H4Me-p)(4)] (2) was prepared by the reaction of InCl3 center dot 3H(2)O and NaSC6H4Me-p in the presence of [Et4N]Cl center dot xH(2)O. The structures of these three complexes, as determined by single-crystal X-ray diffraction, feature well-separated cations and anions with the metal centers of the anions tetrahedrally coordinated to four thiolate or selenolate ligands. The thermal stability of the three complexes was studied by thermal gravimetric analysis. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.07.010