| 165463-04-7

• CAS: 165463-04-7
• 化学式: C₁₄H₃₀N₂O₄Pt₂
• 分子量: 680.563
• InChiKey: OARGEPOEZYPACH-HQLONWRLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trimethylplatinum(IV) sulfate tetrahydrate 、 二乙酰一肟 在 sodium acetate 作用下， 以 水 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Complexes of trimethylplatinum(IV) with butane-2,3-dione monoxime

  摘要：

  The dimeric complex of butane-2,3-dione monoxime (Hbdm) with trimethylplatinum(IV), [{PtMe(3)(bdm)}(2)] 1, and its pyridine (py) and 2,2'-bipyridyl (bipy) adducts [PtMe(3)(bdm)(py)] and [PtMe(3)(bdm)(bipy)], show three different configurations for the ionised monoxime ligand. Dimer 1 forms a fluxional solvated monomer in co-ordinating solvents. Its solution-state stereodynamics in CD,OD have been measured by two-dimensional exchange NMR spectroscopy and a 'windscreen-wiper' mechanism proposed which is novel in trimethylplatinum(IV) chemistry.

  DOI：

  10.1039/dt9950001233