| 252553-72-3

• CAS: 252553-72-3
• 化学式: ClO₄*CoH₁₆N₅O₃P*H₂O
• 分子量: 341.592
• InChiKey: MXGWNINZKGWKHB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Co(NH3)5(dimethylsulfoxide)](ClO4)3 、 、 lithium bromide 以 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  [(NH3)5CoOP(H)(O)OCo(NH3)5]4+ and its conjugate acid; evidence for the P+O− description of a terminal PO bond

  摘要：

  Bromine oxidation of the phosphite-bridged dimer [(NH3)(5)CoOP(H)(O)OCo(NH3)(5)](4+) (1) in acidified aqueous solution (25 degrees C, I = 1.125 M, NaClO4) gives the corresponding phosphato complex [(NH3)(5)CoOP(OH)(O)OCo(NH3)(5)](4+). The reaction follows the rate law k(obs) = kK(a)[dimer](T)/(K-a + [H+])(1 + K-BR3[Br-]), with K-Br3(= [Br-3(-)]/[Br-2][Br-]) = 17.6 M-1, and with K-a (0.074 +/- 0.006 M) corresponding to the acidity constant of the acid conjugate [(NH3)(5)CoOP(H)(OH)OCo(NH3)(5)](5+) (2), and k (1.00 +/- 0.05 M-1 s(-1)) to the rate constant for oxidation of 1. The reaction is interpreted as involving attack by free Br-2 on the O-atom of the terminal P-O group in 1 and rate-determining P-H bond breaking. The acidity constant of 2 was confirmed by independent spectrophotometric determination, K-a= 0.09 +/- 0.01 M, 25 degrees C, I= 1.0 M. Crystal structures are reported for both 1(ClO4)(4). 2H(2)O and 2(ClO4)(5). C2H5OH. The available evidence suggests that the terminal P-O bond in 1 is best represented as a limiting case of the Pdelta+-Odelta- description. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00264-9
• 作为产物：
  描述：

  亚磷酸 、 aquapentaamminecobalt(III) perchlorate 、 lithium perchlorate 在 2,6-lutidine 作用下， 以 水 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  [(NH3)5CoOP(H)(O)OCo(NH3)5]4+ and its conjugate acid; evidence for the P+O− description of a terminal PO bond

  摘要：

  Bromine oxidation of the phosphite-bridged dimer [(NH3)(5)CoOP(H)(O)OCo(NH3)(5)](4+) (1) in acidified aqueous solution (25 degrees C, I = 1.125 M, NaClO4) gives the corresponding phosphato complex [(NH3)(5)CoOP(OH)(O)OCo(NH3)(5)](4+). The reaction follows the rate law k(obs) = kK(a)[dimer](T)/(K-a + [H+])(1 + K-BR3[Br-]), with K-Br3(= [Br-3(-)]/[Br-2][Br-]) = 17.6 M-1, and with K-a (0.074 +/- 0.006 M) corresponding to the acidity constant of the acid conjugate [(NH3)(5)CoOP(H)(OH)OCo(NH3)(5)](5+) (2), and k (1.00 +/- 0.05 M-1 s(-1)) to the rate constant for oxidation of 1. The reaction is interpreted as involving attack by free Br-2 on the O-atom of the terminal P-O group in 1 and rate-determining P-H bond breaking. The acidity constant of 2 was confirmed by independent spectrophotometric determination, K-a= 0.09 +/- 0.01 M, 25 degrees C, I= 1.0 M. Crystal structures are reported for both 1(ClO4)(4). 2H(2)O and 2(ClO4)(5). C2H5OH. The available evidence suggests that the terminal P-O bond in 1 is best represented as a limiting case of the Pdelta+-Odelta- description. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00264-9