| 1044873-14-4

• CAS: 1044873-14-4
• 化学式: C₂₁H₃₄B₁₀NP
• 分子量: 439.591
• InChiKey: BMXDDJHNGKZDMR-XIFFEERXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 双氧水 以 水 、 甲苯 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C₁₃H₈)(ⁱPr₂N)P(−O)(C₂B₁₀H₁₀)]²⁻ and [(C₁₃H₉)(ⁱPr₂N)P(═O)(C₂B₉H₁₀)]²⁻

  摘要：

  Treatment Of (C13H9)((Pr2N)-Pr-i)PC1 with Li2C2B10H10 gave, after neutralization with Me3NHCI, a trivalent phosphorus-bridged compound, (C13H9)((Pr2N)-Pr-i)P(C2B10H11). It was easily converted to a pentavalent phosphorus-bridged ligand, (C13H9)((Pr2N)-Pr-i)P(=0)(C2B10H10) (4), by reacting with excess hydrogen peroxide in toluene. An equimolar reaction of 4 with Zr(NMe2)4 in toluene at room temperature afforded a zirconium amide incorporating a fluorenylide unit, [sigma:sigma(C13H8)((Pr2N)-Pr-i)P(-O)(C2B10H10)]Zr(NMe2)2(THF) (5). Complex 5 was converted to the zirconacarborane [eta(1):eta(5)-(C H-13(9))((Pr2N)-Pr-i)P(=O)(C2B9H10)]Zr(NMe2)2 (6) in refluxing toluene in the presence Of Me2NH. Its titanium analogue, [eta(1):eta(5)-(C H-13(9))((Pr2N)-Pr-i)P(=O)(C2B9H10)]Ti(NMe2)2 (7), was directly prepared from the reaction of 4 with Ti(NMe2)4 in refluxing toluene. Complex 7 reacted with KH in C6D6 to generate the deprotonated product {[eta(1):eta(5)-(C13H8)((Pr2N)-Pr-i)P(=O)(C2B9H10)]Ti(NMe2)2} {(eta(6)-C6D6)2K)} (8). These new complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om800319w
• 作为产物：
  描述：

  1,2-dilithio-o-carborane 、 (R)-1-chloro-1-(9H-fluoren-9-yl)-N,N-diisopropylphosphanamine 、 三甲胺盐酸盐 以 乙醚 、 水 、 甲苯 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C₁₃H₈)(ⁱPr₂N)P(−O)(C₂B₁₀H₁₀)]²⁻ and [(C₁₃H₉)(ⁱPr₂N)P(═O)(C₂B₉H₁₀)]²⁻

  摘要：

  Treatment Of (C13H9)((Pr2N)-Pr-i)PC1 with Li2C2B10H10 gave, after neutralization with Me3NHCI, a trivalent phosphorus-bridged compound, (C13H9)((Pr2N)-Pr-i)P(C2B10H11). It was easily converted to a pentavalent phosphorus-bridged ligand, (C13H9)((Pr2N)-Pr-i)P(=0)(C2B10H10) (4), by reacting with excess hydrogen peroxide in toluene. An equimolar reaction of 4 with Zr(NMe2)4 in toluene at room temperature afforded a zirconium amide incorporating a fluorenylide unit, [sigma:sigma(C13H8)((Pr2N)-Pr-i)P(-O)(C2B10H10)]Zr(NMe2)2(THF) (5). Complex 5 was converted to the zirconacarborane [eta(1):eta(5)-(C H-13(9))((Pr2N)-Pr-i)P(=O)(C2B9H10)]Zr(NMe2)2 (6) in refluxing toluene in the presence Of Me2NH. Its titanium analogue, [eta(1):eta(5)-(C H-13(9))((Pr2N)-Pr-i)P(=O)(C2B9H10)]Ti(NMe2)2 (7), was directly prepared from the reaction of 4 with Ti(NMe2)4 in refluxing toluene. Complex 7 reacted with KH in C6D6 to generate the deprotonated product {[eta(1):eta(5)-(C13H8)((Pr2N)-Pr-i)P(=O)(C2B9H10)]Ti(NMe2)2} {(eta(6)-C6D6)2K)} (8). These new complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om800319w