| 812699-16-4

• CAS: 812699-16-4
• 化学式: C₃₀H₃₀B₂O₈P₂
• 分子量: 602.133
• InChiKey: JMSLURQVLWVBOE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 盐酸 、 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Amino-acid containing metallomonomers copolymerized into porous organic polymers: applicability to allylic alkylation catalysis

  摘要：

  This paper reports the synthesis of a polymerizable dppe-derivative with eight pendent styrenyl units linked to the dppe core through four tyrosine residues. This diphosphine ligand was utilized in the synthesis of a series Of P2PdX2 complexes (X-2 = (R)BINOL, (S)-BINOL, Cl-2 and pi-1,3-Ph-2-allyl(+)). The compounds were used as comonomers for the synthesis of porous organic polymers (poly EDMA). Molecular imprinting effects on X-2-ligand removal were investigated. Overall, the presence of a cavity of significant size was found to be beneficial to the rate of the allylic alkylation reaction, however, chiral BINOL shaped cavities did not influence the enantio-selectivity of the reaction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.04.017