(CO)Rh(bis(benzothiazole-2-yl)methane) tetrafluoroborate | 518041-54-8

• 英文名称: (CO)Rh(bis(benzothiazole-2-yl)methane) tetrafluoroborate
• 英文别名: (Co)2Rh(2,2'-methylenebis[benzothiazole]) tetrafluoroborate
• CAS: 518041-54-8
• 化学式: BF₄*C₁₇H₁₀N₂O₂RhS₂
• 分子量: 528.121
• InChiKey: NCYBBPQOCRKVET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (cycloocta-1,5-diene)Rh(bis(benzothiazole-2-yl)methane) tetrafluoroborate 、 一氧化碳 以 二氯甲烷 为溶剂， 以75%的产率得到(CO)Rh(bis(benzothiazole-2-yl)methane) tetrafluoroborate
  参考文献：
  名称：

  New Rhodium Complexes Coordinated by Bidentate Imine Ligands with Benzothiazolyl Functionalities

  摘要：

  The pseudo-square-planar complexes [Rh(cod)(Hbbtm)]BF4 (3), [Rh(bbte)(cod)]BF4 (4), [Rh(CO)2(Hbbtm)]BF4 (5), [Rh(bbte)(CO)(2)]BF4 (6), [Rh(bbtm)(cod)] (7) and [Rh(bbtm)(CO)(2)] (8) (Hbbtm=bis(benzothiazol-2-yl)methane=2,2'-methylenebis[benzothiazole], bbte=bis(benzothiazol-2-yl)ethane = 2,2'-(ethane-1,2-diyl)bis[benzothiazole], and cod = cycloocta-1,5-diene) were synthesized and characterized. Diastereotopic protons were observed for the protons at the bridge in the H-1-NMR of 3 and 5. Twisting of the ethane-1,2-diyl bridge in 4 and 6 effects chemical equivalence of the CH2 groups in solution. Unusually large downfield shifts occur on coordination of the deprotonated ligand Hbbtm as the negative charge is delocalized in 7 and 8. The NMR signals of the cod ligand in 4 could be differentiated. The X-ray crystal structures of 3, 4, and 6 are reported.

  DOI：

  10.1002/1522-2675(200211)85:11<3737::aid-hlca3737>3.0.co;2-8