fac-[(1,2-bis(diphenylphosphino)methane)(CO)3Mn(C.tplbond.CC5H3CH(Me)NMe2)Fe(C5H5)] | 191677-02-8

• 英文名称: fac-[(1,2-bis(diphenylphosphino)methane)(CO)3Mn(C.tplbond.CC5H3CH(Me)NMe2)Fe(C5H5)]
• CAS: 191677-02-8
• 化学式: C₄₄H₄₀FeMnNO₃P₂
• 分子量: 803.539
• InChiKey: JEUHXJMKEURLQG-JSAMNSCASA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  fac-[(κ₂-dppm)Mn(CO)₃Br] 、 (R)-(S)-N,N-dimethylaminoethylethynylferrocene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以25%的产率得到fac-[(1,2-bis(diphenylphosphino)methane)(CO)3Mn(C.tplbond.CC5H3CH(Me)NMe2)Fe(C5H5)]
  参考文献：
  名称：

  The synthesis of chiral ferrocene ligands and their metal complexes

  摘要：

  Starting from the well known N,N-dimethylaminoethylferrocene (1) {or N,N-dimethyl(1-ferrocenylethyl)amine}, further substitution of the cyclopentadienyl ring in an adjacent position enables formation of -iodo (2), -trimethylsilylethynyl (3) and -ethynyl (4) derivatives in good yields. From 4, fac-[manganese1,2 bis(diphenylphosphinomethane)(tricarbonyl)acetylide] (5), trans-[rutheniumdi(1,2-bis(diphenylphosphinomethane))chloro-acetylide] (6) and trans-[osmiumdi(1,2-bis(diphenylphosphinomethane))chloro-acetylide] (7) have been synthesised and characterised. Electrochemical experiments in solution indicate that there is a decrease in polarisation and a decrease in the degree of metal-to-metal interaction in the chiral ferrocenyl metal-acetylides as opposed to the non-chiral analogues. Second harmonic generation (Kurtz powder) measurements are reported on the chiral metal complexes, but unfortunately negligible second-order non-linear activity was observed.

  DOI：

  10.1016/s0022-328x(96)06727-7