| 525552-97-0

• CAS: 525552-97-0
• 化学式: C₂₅H₃₃Cl₂N₂O₂Sm
• 分子量: 614.815
• InChiKey: AQOSFICVXVBKOR-OOSCDWNUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 Li[(C6H5)NC(CH3)]2CH 、 氯化钐 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Synthesis of lanthanide chlorides supported by β-diketiminate ligands and molecular structures of L1SmCl2(THF)2 and L2SmCl2(THF)2 [L1=PhNC(Me)CHC(Me)NPh; L2=p-ClPhNC(Me)CHC(Me)NPh(2,6-Pri2)]

  摘要：

  The beta-diketiminate lithium salts [(LLi)-Li-1, L-1 = PhNC(Me)CHC(Me)NPh; (LLi)-Li-2, L-2 = p-ClPhNC(Me)CHC(Me)NPh(2,6-Pr-2(i))] reacted with anhydrous LnCl(3) (Ln = Sm, Yb) in 1: 1 molar ratio in THF to afford the new heteroleptic lanthanide complexes L(1)LnCl(2)(THF)(2) (Ln = Sm (1), Yb (2)) and L(2)LnCl(2)(THF)(2) (Ln = Sm (3), Yb (4)) in high yields. The substituents on the arene ring have significant effect on the solubility of these complexes. Crystal structure analysis revealed that complexes I and 3 are both monomeric, in which the samarium atom is coordinated by two nitrogen atoms of the beta-diketiminate ligand, two chloro and two THF ligands in distorted octahedral environment. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01367-0