PdCl(9-anthraldehyde benzoylhydrazonato-κ3-C1,N,O) N,N-dimethylformamide monosolvate | 1357113-92-8

• 英文名称: PdCl(9-anthraldehyde benzoylhydrazonato-κ3-C1,N,O) N,N-dimethylformamide monosolvate
• CAS: 1357113-92-8
• 化学式: C₃H₇NO*C₂₂H₁₅ClN₂OPd
• 分子量: 538.342
• InChiKey: JYIKZKQVZHCPRO-RCPKOPEESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  PdCl(9-anthraldehyde benzoylhydrazonato-κ3-C1,N,O) 、 N,N-二甲基甲酰胺 以 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 生成 PdCl(9-anthraldehyde benzoylhydrazonato-κ3-C1,N,O) N,N-dimethylformamide monosolvate
  参考文献：
  名称：

  Cyclopalladated complexes with 9-anthraldehyde aroylhydrazones: Synthesis, properties and structures

  摘要：

  Reactions of equimolar amounts of Li2PdCl4, 9-anthraldehyde 4-R-benzoylhydrazones (H2Ln; n - 1 and 2 for R = H and NMe2, respectively) and CH3COONa center dot 3H(2)O in methanol produce the cyclopalladated complexes with the formula [Pd(HLn)Cl] (1 (R = H) and 2 (R = NMe2)). Reactions of [Pd(HLn)Cl] (1 and 2) with 2 mol equivalents of PPh3 in acetone provide the complexes of formula [Pd(L-n)(PPh3)] (3 (R = H) and 4 (R = NMe2)). Complexes 1-4 have been characterized by elemental analysis and spectroscopic (IR, UV-vis, fluorescence and NMR) measurements. Molecular structures of 1-4 have been confirmed by X-ray crystallography. In [Pd(HLn)Cl] (1 and 2), the C,N,O-donor (HLn)(-) and the chloride form a CNOCl square-plane around the metal centre, while (L-n)(2-) and the PPh3 assemble a CNOP square-plane around the metal centre in [Pd(L-n)(PPh3)] (3 and 4). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.12.018