bis(1,4,7-trimethylindenyl)iron(II) | 861907-12-2

• 英文名称: bis(1,4,7-trimethylindenyl)iron(II)
• CAS: 861907-12-2
• 化学式: C₂₄H₂₆Fe
• 分子量: 370.317
• InChiKey: XBDKFDXVPKJRHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,4,7-trimethylindene 、 iron(II) chloride 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 以71%的产率得到bis(1,4,7-trimethylindenyl)iron(II)
  参考文献：
  名称：

  Synthesis, structures and spectroelectrochemistry of methyl-substituted bis(η5-indenyl)iron(II) complexes

  摘要：

  Several new methyl-substituted indenyl ferrocenes were prepared by metathesis reactions of the indenide (generated from the appropriate indene with BuLi) with ferrous chloride. The indenides used to prepare new ferrocenes were: 2-methyl-, 1,2-dimethyl-, 4,7-dimethyl-, 1,4,7-trimethyl-, and 1,3,4,7-tetramethyl-indenide. These indenyl ferrocenes, along with those prepared from indenide, 1-methylindenide, and 1,3-dimethylindenide, were then characterized by H-1 and C-13 NMR, UV/visible spectroscopy, cyclic voltammetry and mass spectrometry. The cyclic voltammetry showed an additive relationship between oxidation potential and the number of methyl groups which is also position-dependent, whereas the UV/visible spectra showed two absorptions essentially unaffected by methyl substitution. Additionally, bis(2-methylindenyl)iron(II) and bis(4,7-dimethylindenyl)iron(II) were characterized by X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.03.036