Heteropolyagostic Interactions in Lanthanide(III) Diisopropylamido Complexes
摘要:
A complex containing a diverse ligand set around Nd has been assembled in Nd[(NPr2)-Pr-i][(mu-(NPr2)-Pr-i)(mu u-Me)AlMe2][(mu-Me)(2)AlMe(2)], which contains agostic interactions between the metal and each type of ligand as well as a very short Nd-N bond.
Heteropolyagostic Interactions in Lanthanide(III) Diisopropylamido Complexes
摘要:
A complex containing a diverse ligand set around Nd has been assembled in Nd[(NPr2)-Pr-i][(mu-(NPr2)-Pr-i)(mu u-Me)AlMe2][(mu-Me)(2)AlMe(2)], which contains agostic interactions between the metal and each type of ligand as well as a very short Nd-N bond.