trans-Al(8-hydroxyquinoline(-H))2Cl | 60429-51-8

• 英文名称: trans-Al(8-hydroxyquinoline(-H))2Cl
• 英文别名: Al(8-hydroxyquinoline(-H))2Cl
• CAS: 60429-51-8
• 化学式: C₁₈H₁₂AlClN₂O₂
• 分子量: 350.74
• InChiKey: OZGDTNHBIKKDSS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 氯化二乙基铝 以 四氢呋喃 、 正己烷 为溶剂， 生成 trans-Al(8-hydroxyquinoline(-H))2Cl
  参考文献：
  名称：

  Optical and electrochemical properties and the calculated structure of pentacoordinate aluminum 8-hydroxyquinoline

  摘要：

  In this study we report on the characterization of a series of pentacoordinate aluminum 8-hydroxyquinolines, AlQ(2)X (X = F, Cl, Br), composed of two 8-hydroxyquinoline (8-HQ) groups and one halogen ligand. These were prepared by reacting 8-hydroxyquinoline and dialkylaluminum halide stoichiometrically. The lambda(max)s of absorption and emission were in the range of 385-388 and 515-516 nm, respectively, which were similar to AlQ(3). The molar absorptivity of AlQ(2)X is similar regardless of the X group but emission efficiency of AlQ(2)X is 2-3 fold higher than that of AlQ(3) when X = F or Br, but not when X = Cl. This result can be attributed to decreased quenching of energy due to a less steric environment by reducing quinolinate content. The overall molecular orbital structures and the absorption spectra of AlQ(2)X and AlQ(3) are very similar due to a single quinolinate unit. The value of the potential difference of AlQ(2)Xs between anodic and cathodic waves (Delta E = 3.12 V) is close to the estimated HOMO-LUMO energy gap (the optical band gap, Delta E-optical similar to 1240/lambda(max)), 3.19 eV. Detailed optical and electrochemical properties of AlQ(2)X are discussed. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.04.001