| 147264-67-3

• CAS: 147264-67-3
• 化学式: C₂₃H₃₄Fe
• 分子量: 366.37
• InChiKey: PEKNHVMLEDPRPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  hexamethylbenzenecyclopentadienyliron 、 6-碘-1-己烯 以 四氢呋喃 为溶剂， 生成 、
  参考文献：
  名称：

  19价电子夹心复合物与烷基卤的反应。彻底的调查

  摘要：

  The organometallic radicals COCP2 (1) and CpFe(HMB) (HMB = C6Me6; 2) react with the radical-clock reagent 5-hexenyl iodide to give unrearranged addition products, while with cyclopropylmethylhalides both unrearranged cyclopropylmethyl and rearranged 3-butenyl addition products are formed. The rate constant for radical addition was estimated from the product ratios. For 1 a lower bound of k2 greater-than-or-equal-to 5.8 X 10(8) s-1 at 67-degrees-C was obtained, while for 2 a value of k2 = (1.2 +/-0.2) X 10(9) s-1 at 25-degrees-C was determined. Thus, both 1 and 2 are extremely efficient radical scavengers.

  DOI：

  10.1021/om00028a071