[[((2,6-iPr2C6H3)NC(CH3))2CH]NdCl2(THF)2] | 1145686-63-0

• 英文名称: [[((2,6-iPr2C6H3)NC(CH3))2CH]NdCl2(THF)2]
• CAS: 1145686-63-0；1217299-85-8
• 化学式: C₃₇H₅₇Cl₂N₂NdO₂
• 分子量: 777.018
• InChiKey: MIZBTEPCTLKWKL-CCQMTRPPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [[((2,6-iPr2C6H3)NC(CH3))2CH]NdCl2(THF)2] 、 sodium hexamethyldisilazane 、 甲苯 以 甲苯 为溶剂， 以52%的产率得到[[((2,6-iPr2C6H3)NC(CH3))2CH]Nd(N(SiMe3)2)2]*0.5(toluene)
  参考文献：
  名称：

  Synthesis of Dianionic β-Diketiminate Lanthanide Amides L′LnN(SiMe₃)₂(THF) by Deprotonation of the β-Diketiminate Ligand L (L = {[(2,6-iPr₂C₆H₃)NC(CH₃)]₂CH}⁻) and the Transformation with [HNEt₃][BPh₄] to the Cationic Samarium Amide [LSmN(SiMe₃)₂][BPh₄]

  摘要：

  Reaction of beta-diketiminate lanthanide dichlorides LLnCl(2)(THF)(2) (L = {[(2,6-iPr(2)C(6)H(3))NC(CH3)](2)CH}(-)) with 2 equiv of NaN(SiMe3)(2) in toluene afforded lanthanide amide complexes supported by a dianionic beta-diketiminate ligand L', L'LnN(SiMe3)(2)(THF) (L' = {(2,6-iPr(2)C(6)H(3))NC(CH2)CHC(CH3)N(2,6-iPr(2)C(6)H(3))}(2-), Ln = Yb (1), Y (2), Gd (3), Sm (4)), in moderate yields via deprotonation of L. Addition of a small amount of THF led to an increase of the yields of 1-4. Lanthanide metals have a great influence on the deprotonation of L. The same reaction with LNdCl2(THF)(2) did not afford the analogous complex L'NdN(SiMe3)(2)(THF), but the normal diamide complex LNd[N(SiMe3)(2)](2) (5) was isolated instead. The metathesis reaction of the triply bridged dichlorides of Sm, LSmCl(mu-Cl)(3)SmL(THF), with 2 equiv of NaN(SiMe3)(2) yielded the diamide complexes LSm[N(SiMe3)(2)](2) in toluene, while complex 4 was formed instead in a mixture of toluene and THF. In contrast, the same reactions with LYbCl(mu-Cl)(3)YbL(THF) either in toluene or in a mixture of toluene and THF both afforded 1. Treatment of 4 with [HNEt3][BPh4] in THF at room temperature gave the novel cationic Sm beta-diketiminate amide complex [LSmN(SiMe3)(2)(THF)(2)][BPh4] (7) in good yield. Complexes 1-5 and 7 have been confirmed by single-crystal X-ray structural analyses. The mechanism of deprotonation of L was discussed.

  DOI：

  10.1021/om2010904
• 作为产物：
  描述：

  四氢呋喃 、 N,N′-bis(2,6-diisopropylphenyl)pentane-2,4-diimine 、 三氯化钕 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以72%的产率得到[[((2,6-iPr2C6H3)NC(CH3))2CH]NdCl2(THF)2]
  参考文献：
  名称：

  Tris-β-二酮亚胺镧系元素配合物的合成和结构及其对ε-己内酯和L-丙交酯开环聚合的高活性

  摘要：

  {[(4–XC6H4)NC(Me)]2CH}Li 与无水三氯化镧系元素 (LnCl3) 以 3:1 的摩尔比复分解产生一系列通式为 [LnLX3] [X = Cl, LCl: Ln = Pr (1), Nd (2), Sm (3); X = H, L: Ln = Nd (4); X = Me，LMe：Ln = Nd (5)]。β-二酮亚胺的钠盐与无水 LnCl3 在 thf 中以 1:1 的摩尔比反应得到相应的 β-二酮亚胺镧系元素二氯化物 [LClPrCl2(thf)2] (6), [LMeNdCl2(thf)2] (7),和 [LNdCl2(thf)2] {L = [(2,6-iPr2C6H3)NC(Me)]2CH–} (8)，分别。对这些配合物进行了表征，配合物 1-5 和 8 的分子结构通过 X 射线单晶结构分析确定。发现配合物 1-5 是非常活跃的单组分引发剂，用于在温和条件下 ϵ-己内酯

  DOI：

  10.1002/ejic.200900313