[(Cy3P)2Pt(CO)2] | 79769-84-9

• 英文名称: [(Cy3P)2Pt(CO)2]
• CAS: 79769-84-9
• 化学式: C₃₈H₆₆O₂P₂Pt
• 分子量: 811.968
• InChiKey: FNPGMEBZFDHENR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(三环己基膦)铂(0) 、 一氧化碳 以 甲苯 为溶剂， 生成 [(Cy3P)2Pt(CO)2]
  参考文献：
  名称：

  Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy₃P)₂Pt(CO)] and [(Cy₃P)₂Pt(CO)₂]

  摘要：

  The platinum(0) monocarbonyl complex, [(Cy3P)(2)Pt(CO)], was synthesized by reaction of [(Cy3P)(2)Pt] with [(eta(5)-C5Me5)Ir(CO)(2)] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine ligands. Its corresponding dicarbonyl complex [(Cy3P)(2)Pt(CO)(2)] was synthesized by treatment of [(Cy3P)(2)Pt] with CO at -40 degrees C and confirmed by X-ray structure analysis.

  DOI：

  10.1021/ic102200t

文献信息

• PREPARATION OF SEVERAL NEW TRANSITION METAL HYDRIDO COMPLEXES OF A TYPE MH(Y)L_n(M = Ni, Pd, Pt; Y = IMIDO, ALKENYL CARBOXYLATO) AND ELIMINATION OF HY FROM THE COMPLEXES ON INTERACTION WITH π-ACIDS
  作者：Takakazu Yamamoto、Kenji Sano、Akio Yamamoto

  DOI：10.1246/cl.1982.907

  日期：1982.6.5

  Pd) and trans-PtH(OCOR) (PCy3)2(R = –C(CH3)=CH2, –CH2CH=CH2) have been prepared by oxidative addition of succinimide or the corresponding acid to the zero-valent transition metal complexes. Treatment of the hydrido complexes with π-acids such as CO and maleic anhydride causes elimination of succinimide or RCOOH.

  MH(succinimido) (PCy3)2 (M = Ni, Pd) 和 trans-PtH(OCOR) (PCy3)2(R = –C(CH3)=CH2, – CH= ) 已通过琥珀酰亚胺的氧化加成制备或零价过渡金属络合物的相应酸。用 π-酸如 CO 和马来酸酐处理氢化物复合物导致琥珀酰亚胺或 RCOOH 的消除。