| 97374-99-7

• CAS: 97374-99-7
• 化学式: BF₄*C₂₀H₁₇FeO₂S
• 分子量: 464.071
• InChiKey: RJQNTAHBMOFQSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 顺-环辛烯 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Kinetics and Mechanism of Cyclopropanation of Cyclooctene by [Fe(η⁵-C₅H₅)(CO)₂CH₂SPh₂]BF₄

  摘要：

  The kinetics of reaction of [Fe(eta(5)-C5H5)(CO)(2)CH2SPh2]BF4 with cyclooctene in CH2Cl2 solution have been studied under pseudo-first-order conditions at room temperature. The variation of k(obs) is nonlinear in both cyclooctene and added Ph2S. The results are interpreted in terms of a two-step reaction in which the cation [Fe(eta(5)-C5H5)(CO)(2)CH2SPh2](+) undergoes reversible, dissociative loss of Ph2S followed by competitive capture of the methyleneiron complex by cyclooctene to produce bicyclo[6.1.0]nonane. The methyleneiron intermediate is 4-5 times more reactive toward diphenylsulfide than cyclooctene. In the absence of added Ph2S, millimolar solutions of the iron complex react with cyclooctene at room temperature with a half-life of about 36 min to give >85% yields of bicyclo[6.1.0]nonane after 3 h, and it is thus more reactive than the dimethyl- and methylphenylsulfonium salt analogues.

  DOI：

  10.1021/om980472a
• 作为产物：
  描述：

  (CH2Cl)dicarbonyl(eta.5-cyclopentadienyl)iron 、 四氟化硼(+3)铊(+1) 、 二苯硫醚 以 二氯甲烷 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Kent Barefield; McCarten, Paul; Hillhouse, M. Christine, Organometallics, 1985, vol. 4, # 9, p. 1682 - 1684

  摘要：

  DOI：