Cp*Ni(PEt3)(acc) | 184485-00-5

• 英文名称: Cp*Ni(PEt3)(acc)
• CAS: 184485-00-5
• 化学式: C₂₁H₃₇NiO₂P
• 分子量: 411.187
• InChiKey: JIFPXXDMTRJJJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (acetylacetonato)(η5-pentamethylcycopentadienyl)nickel(II) 、 三乙基膦 以 正戊烷 为溶剂， 以80%的产率得到Cp*Ni(PEt3)(acc)
  参考文献：
  名称：

  Me₅C₅Ni(acac):  A Monomeric, Paramagnetic, 18-Electron, Spin-Equilibrium Molecule

  摘要：

  New synthetic procedures have been developed for Me(5)C(5)M(acac), M = Co or Ni. The crystal structures of these 17- or 18-electron monomers show that the compounds are isomorphous and in space group P (1) over bar, with the planes defined by the Me(5)C(5) ring and the M(acac) fragment perpendicular to within 5 degrees. The Me(5)C(5) ring in both molecules has an ene-allyl distortion which is rationalized by the low molecular symmetry (C-s), which removes the degeneracy in the e(+) and e(-) ring orbitals. The electronic structure of the cobalt compound is (2)A, as deduced from magnetic susceptibility and EPR spectroscopy. The electronic structure of the nickel compound depends upon the temperature. In the solid state, the compound is diamagnetic below 150 K, but it becomes paramagnetic with increasing temperature. The H-1 NMR chemical shifts of the compound in solution are nonlinear in temperature, and a plot of delta vs T-1 yields an equilibrium constant of 0.47 at 303 K for the low spin <----> high spin equilibrium. The 20-electron phosphine complexes of nickel can be isolated; Me(5)C(5)Ni(acac)(PMe(3)) is a simple paramagnet with two unpaired spins, but the PEt(3) complex exists in equilibrium with its base-free compound in solution. The cobalt compound does not give an isolable phosphine complex. A simple symmetry orbital model is proposed that accounts for the electronic and molecular structures of these organometallic compounds.

  DOI：

  10.1021/ja953873f