bis(2-amino-3,5-dibromopyridine)dibromocopper(II) | 1161513-62-7

• 英文名称: bis(2-amino-3,5-dibromopyridine)dibromocopper(II)
• 英文别名: (3,5-diBAP)2CuBr2
• CAS: 1161513-62-7
• 化学式: C₁₀H₈Br₆CuN₄
• 分子量: 727.17
• InChiKey: XWFRTJYQGBXWJO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基-3,5-二溴吡啶 、 copper(ll) bromide 以 乙腈 为溶剂， 以73%的产率得到bis(2-amino-3,5-dibromopyridine)dibromocopper(II)
  参考文献：
  名称：

  Transition metal complexes of 2-amino-3,5-dihalopyridines: Synthesis, structures and magnetic properties of Cu(3,5-diCAP)2X2 and Cu(3,5-diBAP)2X2

  摘要：

  A family of bis(2-amino-3,5-dihalopyridine)dihalocopper(II) compounds has been synthesized, including (3,5-diCAP)(2)CuCl2 (1), (3,5-diCAP)(2)CuBr2 (2), (3,5-diBAP)(2)CuCl2 (3), and (3,5-diBAP) 2CuBr2 (4) [3,5-diCAP = 2-amino-3,5-dichloropyridine; 3,5-diBAP = 2-amino-3,5-dibromopyridine]. These complexes have been analyzed through single crystal X-ray diffraction and temperature dependant magnetic susceptibility. The compounds are all isostructural, forming bi-bridged chains with long Cu-X center dot center dot center dot Cu bridges in the crystal lattice. The two copper chloride compounds (1 and 3) exhibit weak antiferromagnetic interactions along these chains. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.08.031